Brom[thiobis[methan]]kupfer
Bromo(thiobis(methane))copper
Grundinformationen
- CAS
54678-23-8- Standard-SMILES
CSC.[Cu][Br]- InChIKey
PMHQVHHXPFUNSP-UHFFFAOYSA-M- Summenformel
- C2H6BrCuS
- Durchschnittliche Molmasse
- 205,59 g/mol
- Monoisotopische Masse
- 203,86696
Namen und Bezeichner
- Bevorzugter Name
- Bromo(thiobis(methane))copper
- IUPAC
- bromocopper;methylsulfanylmethane
- Lokaler Name
- Brom[thiobis[methan]]kupfer
- Englischer Name
- Copper(I) bromide-dimethyl sulfide
- Summenformel
- C2H6BrCuS
- Molmasse
- 205.58
Namen und Synonyme
54678-23-8Bromo(thiobis(methane))copperBromo[thiobis[methane]]copperEINECS 259-292-5DTXSID80203133RefChem:570302DTXCID80125624Copper(I) bromidedimethyl sulfide complex259-292-5Copper(I) bromide-dimethyl sulfidebromocopper;methylsulfanylmethaneCuBr.Me2S
Weitere Namen anzeigen
COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEXBromocopperCOPPER(I) BROMIDE DIMETHYL SULFIDECopper(I) bromide methyLCopper, bromothiobismethane-COPPER(1)BROMIDE DMS COMPLEXCOPPER BROMIDE-DIMETHYL SULFIDEBROMO(DIMETHYLSULFIDE)COPPER(I)COPPER(1) BROMIDE DMS COMPLEX 95%
bromo(dimethylsulfide)copper (I)(methylsulfanyl)methane; bromocoppercopper (1) bromide-dimethyl sulfideBromidocopper--(methylsulfanyl)methane (1/1)Copper(I)bromide-dimethylsulfideSCHEMBL58269copper(I)bromide dimethylsulfideSCHEMBL41972143
Datenbank-Bezeichner
- CAS
54678-23-8- PubChem CID
- 2724234
- DTXSID
DTXSID80203133- EC Number
- 259-292-5
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 25,3 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 1
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 5
- Formalladung
- 0
- Komplexität
- 4,8
Experimentelle und physikochemische Eigenschaften
Chemical ClassesMetals -> Organic Compounds, Metal Salts
Physical DescriptionOff-white or light green crystals with an unpleasant odor; [Alfa Aesar MSDS]
Physikochemische Eigenschaften
- Schmelzpunkt
- 132 °C · 132 °C (dec.)(lit.)
- Aggregatzustand
- Crystalline Powder and/or Chunks
- Farbe
- Pale brown or pale green
- Wasserlöslichkeit
- Soluble in water. Reacts with water and decomposes.
- BRN
- 4386581 · 4386581
- InChI
- InChI=1S/C2H6S.BrH.Cu/c1-3-2;;/h1-2H3;1H;/q;;+1/p-1
- InChIKey
- PMHQVHHXPFUNSP-UHFFFAOYSA-M
- SMILES
- S(C)C.[Cu]Br
- CAS Datenbank
- 54678 · 54678-23-8(CAS DataBase Reference)
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 45 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Regulatory InformationCopper (I) bromide dimethyl sulfide complex: Does not have an individual approval but may be used under an appropriate group standard
Hazards SummaryDecomposed by water; A skin and strong eye irritant; [Alfa Aesar MSDS] See Copper(I) bromide. See Dimethyl sulfide.
Hazard Classes and CategoriesSkin Irrit. 2 (100%)
Sicherheit und Schutzausrüstung
Exposure Control and Personal Protection0.01 [mg/m3], respirable fraction (Cu, inorganic cmpnds)[German Research Foundation (DFG)]
Threshold Limit Values (TLV)1.0 [mg/m3], as Cu
Permissible Exposure Limit (PEL)1.0 [mg/m3], as Cu
Immediately Dangerous to Life or Health (IDLH)100.0 [mg/m3], as Cu
Chemie und Industrie
Anwendungen
VerwendenCopper(I) bromide-dimethyl sulfide can be used as catalyst for adding Grignard reagents to fullerenes.
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