Dichloro(1,1'-(1,3-propanediyl)bis(1,1-diphenylphosphine-kappaP))nickel

HCID 2724937CAS 15629-92-2
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Grundinformationen

Standard-SMILES
[Cl][Ni][Cl].c1ccc(P(CCCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1
InChIKey
ZBQUMMFUJLOTQC-UHFFFAOYSA-L
Summenformel
C27H26Cl2NiP2
Durchschnittliche Molmasse
542 g/mol
Monoisotopische Masse
540,024022

Namen und Bezeichner

Bevorzugter Name
Dichloro(1,1'-(1,3-propanediyl)bis(1,1-diphenylphosphine-kappaP))nickel
IUPAC
dichloronickel;3-diphenylphosphanylpropyl(diphenyl)phosphane
Englischer Name
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
Summenformel
C27H26Cl2NiP2
Molmasse
542.04

Namen und Synonyme

15629-92-2RefChem:586663Dichloro(1,1'-(1,3-propanediyl)bis(1,1-diphenylphosphine-kappaP))nickel1,3-Bis(diphenylphosphino)propane nickel(II) chloride[1,3-Bis(diphenylphosphino)propane]nickel(II) chlorideNi(dppp)Cl2[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)(1,3-dppp)NiCl21,3-Bis(diphenylphosphino)propane nickel (II) chloride1,3-Bis(diphenylphosphino)propane nickel(II)chloridedichloronickel;3-diphenylphosphanylpropyl(diphenyl)phosphaneNiCl2(dppp)
Weitere Namen anzeigen
NiCl2(DPPP)NiCl2(DPPP)1.3-Bis(dipheny phosphine) propane nickel(II)chlorideDichloro[bis(1,3-diphenylphosphino)propane]nickel(II)1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride1,3-B
C27H26Cl2NiP2(1,3-Bis(diphenylphosphino)propane)dichloronickel; 1,3-Bis(diphenylphosphino)nickel Dichloride; Dichloro[1,3-bis(diphenylphosphino)propane]nickel; Nickel 1,3-Bis(diphenylphosphino)propane Dichloride; (1,3-dppp)NiCl2;SCHEMBL6328AKOS005259144AC-4982FD14035[1,3-Bis(diphenylphosphino)propane] dichloronickel?3-diphenylphosphanylpropyl(diphenyl)phosphane dichloronickel

Datenbank-Bezeichner

CAS
15629-92-2
PubChem CID
2724937
EC Number
605-052-3

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
8
Schwere Atome
32

Physikochemische Eigenschaften

Schmelzpunkt
213 °C · 213 °C (dec.)(lit.)
storage temp.
Inert atmosphere,Room Temperature
Aggregatzustand
crystal
Farbe
red
Wasserlöslichkeit
insoluble
InChI
InChI=1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Danger

H315 (99.2%): Causes skin irritation [Warning Skin corrosion/irritation]；H317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H319 (99.2%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H334 (34.7%): May cause allergy or asthma symptoms or breathing difficulties if inhaled [Danger Sensitization, respiratory]；H335 (98.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H350 (92.6%): May cause cancer [Danger Carcinogenicity]

P203, P233, P260, P261, P264, P264+P265, P271, P272, P280, P284, P302+P352, P304+P340, P305+P351+P338, P318, P319, P321, P332+P317, P333+P317, P337+P317, P342+P316, P362+P364, P403, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 121 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Regulatory InformationRestricted substance: Nickel, dichloro[1,1'-(1,3-propanediyl)bis[1,1-diphenylphosphine-[?]P]]-；EC: 605-052-3；Restriction condition document: PDF link
Hazard Classes and CategoriesSkin Irrit. 2 (99.2%)；Skin Sens. 1 (100%)；Eye Irrit. 2 (99.2%)；Resp. Sens. 1 (34.7%)；STOT SE 3 (98.3%)；Carc. 1A (92.6%)

Regulatorische Informationen

Regulatory InformationRestricted substance: Nickel, dichloro[1,1'-(1,3-propanediyl)bis[1,1-diphenylphosphine-[?]P]]-；EC: 605-052-3；Restriction condition document: PDF link

Sicherheitsdaten

F
10-21
wgk
3
tsca
No
ridadr
3282
hs_code
29319090
risk_code
49-36/37/38-42/43-40

Chemie und Industrie

Anwendungen · 1 Eintrag

Verwenden[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

Vor- und nachgelagerte Produkte

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国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]

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