Methane

HCID 297CAS 74-82-8

Grundinformationen

Standard-SMILES
C
InChIKey
VNWKTOKETHGBQD-UHFFFAOYSA-N
Summenformel
CH4
Durchschnittliche Molmasse
16,043 g/mol
Monoisotopische Masse
16,03130013

Überblick

Methane is a colorless odorless gas. It is also known as marsh gas or methyl hydride. It is easily ignited. The vapors are lighter than air. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket. It is used in making other chemicals and as a constituent of the fuel, natural gas.

Namen und Bezeichner

Bevorzugter Name
Methane
IUPAC
methane
Englischer Name
Methane
Summenformel
CH4
Molmasse
0

Namen und Synonyme

methaneMarsh gasMethyl hydrideFire DampBiogas74-82-8R 50 (refrigerant)metanotetrahydridocarbonHSDB 167Methane in gaseus stateUN1972
Weitere Namen anzeigen
BRN 1718732OP0UW79H66UN1971CH4DTXSID8025545UNII-OP0UW79H66CHEBI:16183R 50

Datenbank-Bezeichner

CAS
74-82-8、8006-14-2
PubChem CID
297
DTXSID
DTXSID8025545
ChEMBL
CHEMBL17564
ChEBI
CHEBI:16183
UNII
OP0UW79H66
EC Number
200-812-7、927-905-1
Nikkaji
J2.228.533E、J2.380I、J3.470.363I、J593B、J68.119I

Eigenschaften

Berechnete Struktureigenschaften

XLogP
0,6
Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
0
Schwere Atome
1

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Toxic Gases & Vapors -> Simple Asphyxiants

Flammable agents - 4th degree

SpringerMaterials PropertiesDunham energy parameter
LogP · 3 Einträge

log Kow = 1.09

1.09

1.09

Odor · 2 Einträge

Odorless

Weak odor

TasteTasteless
Density · 4 Einträge

0.415 to 0.45 at -259.6 °F (USCG, 1999)

0.422 at -256 °F (USCG, 1999) - Less dense than water; will float

0.554 at 0 °C/4 °C (air = 1 ) or 0.7168 g/liter

0.4228 @ -162°C

Physikochemische Eigenschaften

Schmelzpunkt
-182.6 °C · -182.6 °C
Siedepunkt
-161.4 °C · -161.4 °C
Dichte
0.7168 g/cm3 · 0.7168 g/cm3

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H220: Extremely flammable gas [Danger Flammable gases]

P203, P210, P222, P280, P377, P381, and P403 (click each P-code to see the statement)

Danger

H220 (100%): Extremely flammable gas [Danger Flammable gases]

P203, P210, P222, P280, P282, P336+P317, P377, P381, P403, and P410+P403 (click each P-code to see the statement)

Gefahrenhinweise

Regulatory Information · 5 Einträge

Chemical: Methane

Methane is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Methane are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 23-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/14250

Methane or natural gas but excluding refrigerated liquid methane or natural gas: HSNO Approval: HSR001005 Approved with controls

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Methane: Human health tier I assessment
DOT Label · 4 Einträge

Flammable Gas

Flammable Gas

Flammable Gas

Flammable Gas

Fire Hazards · 6 Einträge

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Special Hazards of Combustion Products: None (USCG, 1999)

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· EXTREMELY FLAMMABLE.

· EXTREMELY FLAMMABLE.

Fire Potential · 2 Einträge

Very dangerous fire and explosion hazard when exposed to heat or flame.

Flammable in the presence of an oxidizing gas (eg air), a source of ignition, and when the concentration of the gas is between the lower and upper explosive limits. Keep away from heat/sparks/open flame/hotsurface/oxidizing gas. No smoking.

Health Hazards · 6 Einträge

If concentration of gas is high enough, may cause asphyxiation. No detectable systemic effects, even at 5% concentration in air. (USCG, 1999)

High concentrations may cause asphyxiation. No systemic effects, even at 5% concentration in air. (USCG, 1999)

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.

· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.

Sicherheit und Schutzausrüstung

Fire Fighting · 5 Einträge

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with water spray, powder, carbon dioxide. In case of fire: keep cylinder cool by spraying with water. Combat fire from a sheltered position.

First Aid Measures · 3 Einträge

Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.

ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Accidental Release Measures · 4 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 6 Einträge

Remove victim to open air. If he is overcome by gas, apply artificial resuscitation. (USCG, 1999)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

General First Aid:

General First Aid:

Safe StorageFireproof. Cool. Ventilation along the floor and ceiling.
Exposure Control and Personal Protection · 2 Einträge

· Wear positive pressure self-contained breathing apparatus (SCBA).

· Wear positive pressure self-contained breathing apparatus (SCBA).

Toxikologische Informationen

TreatmentAsphyxiation should be treated by moving the affected person to an uncontaminated area, then giving artificial respiration and administering oxygen, if necessary. (L173)
Health EffectsMethane is an asphyxiant and displaces oxygen in enclosed spaces. At high enough concentrations, oxygen depletion may cause asphyxiation, resulting in generalized hypoxia and possibly death. (L171, L172)
Environmental Fate · 3 Einträge

TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 9(SRC), determined from a log Kow of 1.09(2) and a regression-derived equation(3), indicates that methane is expected to have very high mobility in soil(SRC). Volatilization of methane from moist soil surfaces is expected to be an important fate process(SRC) given an estimated Henry's Law constant of 0.66 atm-cu m/mole(SRC), derived from its vapor pressure, 4.66X10+5 mm Hg(4), and water solubility, 22 mg/L(5). Methane is expected to volatilize from dry soil surfaces(SRC) based upon its vapor pressure(4). An average utilization of 55% for methane by anaerobic soil microorganisms(6) suggests that biodegradation may be an environmental fate process in soil(SRC).

AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 9(SRC), determined from a log Kow of 1.09(2) and a regression-derived equation(3), indicates that methane is not expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is expected(4) based upon an estimated Henry's Law constant of 0.66 atm-cu m/mole(SRC), derived from its vapor pressure, 4.66X10+5 mm Hg(5), and water solubility, 22 mg/L(6). Using this Henry's Law constant and an estimation method(4), volatilization half-lives for a model river and model lake are 2 hours(SRC). According to a classification scheme(7), an estimated BCF of 2(SRC), from its log Kow(2) and a regression-derived equation(3), suggests the potential for bioconcentration in aquatic organisms is low(SRC). The biodegradation half-life of methane was estimated to range from 70 days to infinity in model anaerobic estuarine ecosystems(8), indicating that biodegradation is not an important environmental fate process in water(SRC).

ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), methane, which has a vapor pressure of 4.66X10+5 mm Hg at 25 °C(2), is expected to exist solely as a gas in the ambient atmosphere. Gas-phase methane is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be 4 yrs(3), calculated from its rate constant of 6.85X10-15 cu cm/molecule-sec at 25 °C(4). Methane does not contain chromophores that absorb at wavelengths >290 nm(5) and, therefore, is not expected to be susceptible to direct photolysis by sunlight(SRC).

Adverse EffectsOther Poison - Simple Asphyxiant
Exposure Routes · 2 Einträge

The substance can be absorbed into the body by inhalation.

Inhalation (L172)

Toxicity Summary · 1 Eintrag

Methane is an asphyxiant and displaces oxygen in enclosed spaces. At high enough concentrations, oxygen depletion may cause asphyxiation. Low concentrations of surrounding oxygen results in deficient oxygen to the organs, compounded by increased oxygen exhalation during respiration. This results in generalized hypoxia and possibly death. (L171, A120)

Regulatorische Informationen

DHS Chemicals of Interest (COI) · 4 Einträge

Methane

1

10000

Flammable chemical that can be released at a facility.

Sicherheitsdaten

Alarmwort
Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code H220

Chemie und Industrie

Pharmakologische Informationen

Metabolism/Metabolites · 3 Einträge

Methane is absorbed through the lungs in mammals. when inhaled, the majority of the absorbed dose is exhaled unchanged. A small amount of methane is converted to methanol and ultimately to carbon dioxide. Uptake in humans is less rapid than in the rat.

Small amt of methane undergoes metabolism to methanol and ultimately to carbon dioxide.

Methane is biologically inactive. (L172)

Absorption, Distribution and Excretion · 2 Einträge

The pharmacokinetics of methane ... would probably be similar to that reported for ethane.

Methane has been demonstrated to be absorbed through the lungs in mammals.

Tissue LocationsAdipose Tissue
Cellular LocationsCytoplasm

Verwendung und Herstellung

Uses · 6 Einträge

In the USA 85% of natural gas is methane. [Merck Index] Produced by decaying matter in swamps and marshes; [Hawley]

Mining [Category: Industry]

Smoking cigarettes [Category: Food & Drugs]

In the production of methanol

Constituent of illuminating and cooking gas; in manufacture of hydrogen, hydrogen cyanide, ammonia, acetylene, formaldehyde, in organic syntheses.

Chemical intermediate (excluding fuel use); constituent of natural gas (about 85% methane); ... halogenated methanes, carbon disulfide, sodium hydrosulfide, carbon black

ImpuritiesMethanol and carbon monoxide
U.S. Exports · 3 Einträge

(1972) 7.8X10+10 CU FT (NATURAL GAS)

(1975) 7.0X10+10 CU FT (NATURAL GAS)

(1984) 1.70X10+11 g /NATURAL GAS, METHANE AND MIXTURES THERE OF INCLUDING SYNTHETIC NATURAL GAS/

U.S. Imports · 4 Einträge

(1972) 1.02X10+12 CU FT (NATURAL GAS)

(1975) 9.7X10+11 CU FT (NATURAL GAS)

(1984) 3.80X10+11 g /NATURAL GAS, METHANE AND MIXTURES THEREOF INCLUDING SYNTHETIC NATURAL GAS/

(1986) 7.26X10+8 mcf /Natural gas, methane and mixtures thereof including synthetic natural gas/

U.S. Production · 6 Einträge

2023: 4,000,000,000 - <5,500,000,000 lb

(1972) 2.25X10+13 CU FT (NATURAL GAS)

(1975) 2.01X10+13 CU FT (NATURAL GAS)

(1982) 509.1 MILLION BARRELS

Methane is listed as a High Production Volume (HPV) chemical (65FR81686). Chemicals listed as HPV were produced in or imported into the U.S. in >1 million pounds in 1990 and/or 1994. The HPV list is based on the 1990 Inventory Update Rule. (IUR) (40 CFR part 710 subpart B; 51FR21438).

For more U.S. Production (Complete) data for METHANE (7 total), please visit the HSDB record page.

Consumer UsesFuel

Anbieter33 Anbieter

安徽旺山旺水特种气体有限公司15906197626 · [email protected]
江西核研院新材料有限公司18901398682 18901398682 · [email protected]
湖南省华中特种气体有限公司0734-8755555 15674722888 · [email protected]
Shanghai Enviko Biotechnologyg Co.,Ltd+86-13918629532 +86-13918629532 · [email protected]
济南源茂化工有限公司15665725027 18854103888 · [email protected]

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