Benzyl(methoxymethyl)((trimethylsilyl)methyl)amine

HCID 353442CAS 93102-05-7
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Grundinformationen

Standard-SMILES
COCN(Cc1ccccc1)C[Si](C)(C)C
InChIKey
RPZAAFUKDPKTKP-UHFFFAOYSA-N
Summenformel
C13H23NOSi
Durchschnittliche Molmasse
237,41 g/mol
Monoisotopische Masse
237,15489089

Namen und Bezeichner

Bevorzugter Name
Benzyl(methoxymethyl)((trimethylsilyl)methyl)amine
IUPAC
N-(methoxymethyl)-1-phenyl-N-(trimethylsilylmethyl)methanamine
Englischer Name
N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
Summenformel
C13H23NOSi
Molmasse
237.41

Namen und Synonyme

benzyl(methoxymethyl)[(trimethylsilyl)methyl]amineBenzyl(methoxymethyl)((trimethylsilyl)methyl)amineRefChem:566907630-326-493102-05-7N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamineN-benzyl-1-methoxy-N-((trimethylsilyl)methyl)methanamineN-(methoxymethyl)-1-phenyl-N-(trimethylsilylmethyl)methanamineMFCD00674005N-Benzyl-N-(methoxymethyl)-N-trimethylsilylmethylaminen-methoxymethyl-n-(trimethylsilylmethyl)benzylamineC13H23NOSi
Weitere Namen anzeigen
N-Benzyl-N-(methoxymethyl)trimethylsilylmethylamineN-benzyl(methoxy)-N-((trimethylsilyl)methyl)methanamine)-N-trimethyLcas:93102-05-7-N-(methoxymethyLN-(Methoxymethyl)-N-(trimethyl
N-(Methoxymethyl)-N-(trimethylsilylmethyl)-benzylamineN-Benzyl-1-methoxy-N-[(trimethylsilyl)methyl]methanamineS00978F0001-2246N-benzyl-N-methoxymethyl-N-(trimethylsilylmethyl)amineN-benzyl-1-methoxy-N-[(trimethylsilyl)methyl)methanamineN-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amineN-(Methoxymethyl)-N-[(trimethylsilyl)methyl]benzenemethanamine (>90%)

Datenbank-Bezeichner

CAS
93102-05-7
PubChem CID
353442
DTXSID
DTXSID30326563
EC Number
630-326-4
Nikkaji
J436.255A

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
12,5 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
6
Schwere Atome
16

Physikochemische Eigenschaften

Siedepunkt
76 °C0.3 · 76 °C0.3 mm Hg(lit.)
Dichte
0.928 g/mL · 0.928 g/mL at 25 °C(lit.)
Brechungsindex
20 · n20/D 1.492(lit.)
Flammpunkt
151 °F · 151 °F
storage temp.
Keep in dark place,Sealed in dry,Room Temperature
Löslichkeit
Soluble in chloroform, ethyl acetate.

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (98.1%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 52 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (98.1%)

Sicherheitsdaten

wgk
3
ridadr
1993
hs_code
29319090
risk_code
36/37/38
hazard_code
Xi
safety_code
26-37/39

Chemie und Industrie

Anwendungen

VerwendenN-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine is useful reagent in synthesizing N-benzyl substituted pyrrolidines by [3+2] cycloaddition to α,ßunsaturated esters.

Darstellung · 1 Eintrag

synthetischemost conveniently prepared by treatment of benzylamine with chloromethyltrimethylsilane followed by formaldehyde and methanol.Access to higher ether homologs is achieved by replacing methanol with the appropriate alcohol. An alternate procedure involves alkylation of lithium N-benzyltrimethylsilymethylamide with methoxymethyl chloride.

Vor- und nachgelagerte Produkte

Anbieter50 Anbieter

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]
韶远科技（上海）有限公司021-50795510 4000665055 · [email protected]

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