CAS 21324-39-0 Sodium hexafluorophosphate (HCID 5147921)

Namen und Bezeichner

Bevorzugter Name: Sodium hexafluorophosphate
IUPAC: sodium hexafluorophosphate
Lokaler Name: Natriumhexafluorophosphat
Englischer Name: Sodium hexafluorophosphate
Summenformel: F6NaP
Molmasse: 167.95

Namen und Synonyme

Sodium hexafluorophosphate21324-39-0sodium;hexafluorophosphateMFCD00011122sodium hexafluorophosphate(v)NaPF6SODIUMHEXAFLUOROPHOSPHATEphosphate(1-), hexafluoro-, sodium (1:1)Hexafluorophosphoric acid sodium saltsodium,hexafluorophosphatesodium hexa-fluoro phosphateF6NaP

Weitere Namen anzeigen

10ppm H2O)10ppm H 2 O）Sodium hexafLSodium fluophosphateSodium hexafluorophoSodiumHexafluorophosphate>Sodiumhexafluorophosphate,99%SODIUM HEXAFLUOROPHOSPHATE (V)

sodium hexaflurophosphateCHEMBL3327018SCHEMBL26132576Sodium hexafluoridophosphate(1-)Sodium Hexafluorophosphate(SHFP)DTXSID30943875CHEBI:172377Sodium hexafluorophosphate (SHFP)

Datenbank-Bezeichner

CAS: 21324-39-0
PubChem CID: 5147921
DTXSID: DTXSID30943875
ChEMBL: CHEMBL3327018
ChEBI: CHEBI:172377
EC Number: 244-333-1

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 0 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 7
Frei drehbare Bindungen: 0
Schwere Atome: 8
Formalladung: 0
Komplexität: 67

Experimentelle und physikochemische Eigenschaften

Physical DescriptionWhite odorless crystals; Hygroscopic; [Alfa Aesar MSDS]

Physikochemische Eigenschaften

Schmelzpunkt: 200 °C · >200 °C (lit.)
Dichte: 2.369 g/mL · 2.369 g/mL at 25 °C (lit.)
storage temp.: Store at room temperature, keep dry and cool
Löslichkeit: 2 O: · H2O: soluble5%, clear, colorless
Aggregatzustand: Crystals
Wichte: 3.375 · 3.375
Farbe: White to light gray
PH: 2 · 2.0-4.0
Wasserlöslichkeit: SOLUBLE
Stabilität: Stable. Incompatible with strong acids.
Major Application: battery manufacturing
InChI: InChI=1S/F6P.Na/c1-7(2,3,4,5)6;/q-1;+1
InChIKey: KMADQUOCJBLXRP-UHFFFAOYSA-N
SMILES: [P+5]([F-])([F-])([F-])([F-])([F-])[F-].[Na+]
CAS Datenbank: 21324 · 21324-39-0(CAS DataBase Reference)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Danger

H302 (96.1%): Harmful if swallowed [Warning Acute toxicity, oral]；H312 (96.1%): Harmful in contact with skin [Warning Acute toxicity, dermal]；H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H332 (96.1%): Harmful if inhaled [Warning Acute toxicity, inhalation]

P260, P261, P264, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P362+P364, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 51 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Hazards SummaryCauses burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Harmful by ingestion, inhalation, and skin absorption; [Alfa Aesar MSDS]

Hazard Classes and CategoriesAcute Tox. 4 (96.1%)；Acute Tox. 4 (96.1%)；Skin Corr. 1B (100%)；Acute Tox. 4 (96.1%)

Sicherheit und Schutzausrüstung

Exposure Control and Personal Protection · 2 Einträge

Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

Threshold Limit Values (TLV)2.5 [mg/m3], as F

Permissible Exposure Limit (PEL)2.5 [mg/m3], as F

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.；Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

Sicherheitsdaten

F: 3-10
wgk: 3
ridadr: UN 3260 8/PG 2
hs_code: 28269090
risk_code: 20/21/22-34
hazard_code: C,Xi
hazard_note: Irritant
safety_code: 26-36/37/39-45
hazard_class: 6.1
packing_group: III
Speicherklasse: 8A - Combustible corrosive hazardous materials
Hazard Classifications: Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralEye Dam. 1Skin Corr. 1B

Chemie und Industrie

Anwendungen

VerwendenSodium hexafluorophosphate is used as an ion pairing agent for the determination of cobalt(II) in water samples. It is used as an important raw material in the preparation of 2-chloro-1,3-bis(dimethylamino)trimethinium hexafluorophosphate.