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Natriumhexafluorophosphat
NaPF6 · 10ppm H2O) · 10ppm H 2 O） · Sodium hexafL · Sodium fluophosphate · Sodium hexafluoropho · SODIUM HEXAFLUOROPHOSPHATE · SodiumHexafluorophosphate>Sodiumhexafluorophosphate,99%
Identifikatoren & physikalische Daten
| CAS No. | 21324-39-0 |
|---|---|
| Summenformel | F6NaP |
| Durchschnittliche Molmasse | 167,954 g/mol |
| Monoisotopische Masse | 167,95395025 g/mol |
| SMILES | F[P-](F)(F)(F)(F)F.[Na+] |
| InChIKey | KMADQUOCJBLXRP-UHFFFAOYSA-N |
| PubChem CID | 5147921 |
| ChEMBL | CHEMBL3327018 |
| ChEBI | CHEBI:172377 |
| EC No. | 244-333-1 |
| DTXSID | DTXSID30943875 |
| Lokaler Name | Natriumhexafluorophosphat |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 0 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 7 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 8 |
| Formalladung | 0 |
| Komplexität | 67 |
| Physical Description | White odorless crystalsHygroscopic[Alfa Aesar MSDS] |
| Schmelzpunkt | >200 °C (lit.) |
| Dichte | 2.369 g/mL at 25 °C (lit.) |
| Lagerbedingungen | Store at room temperature, keep dry and cool |
| Löslichkeit | H2O: soluble5%, clear, colorless |
| Aggregatzustand | Crystals |
| Wichte | 3.375 |
| Farbe | White to light gray |
| pH | 2.0-4.0 |
| Stabilität | Stable. Incompatible with strong acids. |
| Hauptanwendungen | battery manufacturing |
| InChI | InChI=1S/F6P.Na/c1-7(2,3,4,5)6/q-1+1 |
| InChIKey | KMADQUOCJBLXRP-UHFFFAOYSA-N |
| SMILES | [P+5]([F-])([F-])([F-])([F-])([F-])[F-].[Na+] |
| CAS Datenbank | 21324-39-0(CAS DataBase Reference) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH302 (96.1%): Harmful if swallowed [Warning Acute toxicity, oral]H312 (96.1%): Harmful in contact with skin [Warning Acute toxicity, dermal]H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]H332 (96.1%): Harmful if inhaled [Warning Acute toxicity, inhalation]P260, P261, P264, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P362+P364, P363, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 51 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| Gefahrenübersicht | Causes burnsInhalation may cause corrosive injuries to upper respiratory tract and lungsHarmful by ingestion, inhalation, and skin absorption[Alfa Aesar MSDS] |
| Hazard Classes and Categories | Acute Tox. 4 (96.1%)Skin Corr. 1B (100%) |
| Expositionsschutz und Persönliche Schutzausrüstung | Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift(Repeated measurements recommended.)1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)] |
| Threshold Limit Values (TLV) | 2.5 [mg/m3], as F |
| Permissible Exposure Limit (PEL) | 2.5 [mg/m3], as F |
| Unerwünschte Wirkungen | Dermatotoxin - Skin burns.Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors. |
| F | 3-10 |
| Wassergefährdungsklasse (WGK) | 3 |
| UN-Transportnummer | UN 3260 8/PG 2 |
| Zollcode | 28269090 |
| R-Sätze (R) | 20/21/22-34 |
| Gefahrensymbole | C,Xi |
| hazard_note | Irritant |
| Sicherheitshinweise (S) | 26-36/37/39-45 |
| Gefahrenklasse | 6.1Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralEye Dam. 1Skin Corr. 1B |
| Verpackungsgruppe | III |
| Lagerklasse | 8A - Combustible corrosive hazardous materials |
Anwendungen & Verwendung
Verwenden
Sodium hexafluorophosphate is used as an ion pairing agent for the determination of cobalt(II) in water samples. It is used as an important raw material in the preparation of 2-chloro-1,3-bis(dimethylamino)trimethinium hexafluorophosphate.
Herstellung & Synthese
synthetische
Prepared by slowly adding PCl5 dropwise to an aqueous HF solution containing NaCl.