Grundinformationen
- Standard-SMILES
N#C[S-].[K+]- InChIKey
ZNNZYHKDIALBAK-UHFFFAOYSA-M- Summenformel
- CKNS
- Durchschnittliche Molmasse
- 97,18 g/mol
- Monoisotopische Masse
- 96,93885166
Namen und Bezeichner
- Bevorzugter Name
- Potassium thiocyanate
- IUPAC
- potassium thiocyanate
- Lokaler Name
- Kaliumthiocyanat
- Englischer Name
- Potassium thiocyanate
- Summenformel
- CKNS
- Molmasse
- 98.19
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
333-20-0- PubChem CID
- 516872
- DTXSID
DTXSID7029619- ChEMBL
CHEMBL2106973- ChEBI
CHEBI:30951- UNII
- TM7213864A
- EC Number
- 206-370-1
- Nikkaji
- J3.633A
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 24,8 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 2
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 4
- Formalladung
- 0
- Komplexität
- 34
Experimentelle und physikochemische Eigenschaften
Density
1.9 g/cm³
1.89 @25 °C
Melting Point
173 °C
173 °C
Physical Description
Colorless deliquescent solid; [Merck Index]
COLOURLESS-TO-WHITE HYGROSCOPIC CRYSTALS.
Physikochemische Eigenschaften
- Schmelzpunkt
- 173 °C · 173 °C (lit.)
- Siedepunkt
- 500 °C · 500°C
- Dichte
- 1.886 · 1.886
- Dampfdruck
- 0.001 hPa · <0.001 hPa (20 °C)
- Flammpunkt
- 500 °C · 500°C
- storage temp.
- 5 °C · Store at +5°C to +30°C.
- Löslichkeit
- 2 O: · H2O: 8 M at 20 °C, clear, colorless
- Aggregatzustand
- Liquid
- pka
- 0.85 · 0.85(Temp: 25 °C)
- Wichte
- 1.886 · 1.886
- Farbe
- colorless or white
- PH
- 5.3 · 5.3-8.7 (25℃, 50mg/mL in H2O)
- Geruch (Odor)
- Odorless
- Wasserlöslichkeit
- 2170 g/L · 2170 g/L (20 ºC)
- Spezifische Wärmekapazität
- 0.91 J/ · Cp(crystal): 0.91 J/(g·K), at 25℃
- Merck
- 14 · 14,7691
- BRN
- 3594799 · 3594799
- Stabilität
- Stable. Incompatible with nitric acid, strong oxidizing agents, active halogen compounds.
- Kosmetik-Inhaltsstoffe Funktionen
- LIGHT STABILIZER
- InChI
- 1S/CHNS.K/c2-1-3;/h3H;/q;+1/p-1
- InChIKey
- ZNNZYHKDIALBAK-UHFFFAOYSA-M
- SMILES
- [K]SC#N
- LogP
- 0.58 · 0.58
- CAS Datenbank
- 333 · 333-20-0(CAS DataBase Reference)
- NIST chemische Informationen
- Potassium thiocyanate(333-20-0)
- EPA chemische Informationen
- Potassium thiocyanate (333-20-0)
- Absorption
- 274 nm · cut-off at 274nm in H2O at 8M
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
Danger
H302+H312+H332 (45.4%): Harmful if swallowed, in contact with skin or if inhaled [Warning Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation];H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral];H312 (99.6%): Harmful in contact with skin [Warning Acute toxicity, dermal];H318 (29.2%): Causes serious eye damage [Danger Serious eye damage/eye irritation];H319 (28.2%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H332 (99.6%): Harmful if inhaled [Warning Acute toxicity, inhalation];H400 (13.4%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard];H412 (81%): Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]
P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P305+P354+P338, P317, P321, P330, P337+P317, P362+P364, P391, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 284 reports by companies from 24 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
Gefahrenhinweise
Regulatory Information
Chemical: Thiocyanic acid, potassium salt
Commission Regulation (EU) No 188/2011
Thiocyanic acid, potassium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Thiocyanic acid, potassium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
05/751/EC, Reg. (EU) No 108/2014
Status: Active Update: 24-06-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/5157
Potassium thiocyanate: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary
Toxic effects include skin eruptions, psychosis, and collapse; [Merck Index] May cause CNS effects (excitement and convulsions); Prolonged or repeated exposure may cause thyroid and CNS effects leading to impaired function and hypothyroidism; [ICSC] Human ingestion of 80 mg/kg causes hallucinations, convulsions, and muscle weakness; Human ingestion of 428 mg/kg causes toxic psychosis, hallucinations, and gastritis; [RTECS] Sheep exposed orally during gestation produced goiter in newborn lambs; Effects to female fertility observed in rats at high doses; Another study demonstrated maternal and fetal toxicity with no increase in congenital defects; [REPROTOX] Harmful by ingestion, inhalation, and skin absorption; Targets the CNS, cardiovascular system, and thyroid; [Sigma-Aldrich MSDS] See Sodium thiocyanate.
Hazard Classes and Categories
Acute Tox. 4 (100%);Acute Tox. 4 (99.6%);Eye Dam. 1 (29.2%);Eye Irrit. 2 (28.2%);Acute Tox. 4 (99.6%);Aquatic Acute 1 (13.4%);Aquatic Chronic 3 (81%)
Acute toxicity - category 4;Eye irritation - category 2A
Acute toxicity (Oral) - Category 4;Specific target organ toxicity - Repeated exposure - Category 1 (thyroid);Hazardous to the aquatic environment (Acute) - Category 3
Sicherheit und Schutzausrüstung
First Aid Measures
Fresh air, rest.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer for medical attention .
Toxikologische Informationen
Signs and Symptoms
Cough. Further see Ingestion.
Confusion. Convulsions. Nausea. Vomiting. Weakness.
Regulatorische Informationen
Regulatory Information
Chemical: Thiocyanic acid, potassium salt
Commission Regulation (EU) No 188/2011
Thiocyanic acid, potassium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Thiocyanic acid, potassium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
05/751/EC, Reg. (EU) No 108/2014
Status: Active Update: 24-06-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/5157
Potassium thiocyanate: Does not have an individual approval but may be used under an appropriate group standard
Sicherheitsdaten
- wgk
- 1
- tsca
- TSCA listed
- hs_code
- 28380000
- RTECS-Nr.
- XL1925000
- risk_code
- 32-52/53-20/21/22
- Toxizität
- LD50 orally in mice, rats: 594, 854 mg/kg, Andersen, Chen, J. Am. Pharm. Assoc. 29, 152 (1940)
- hazard_code
- Xn,Xi
- hazard_note
- Irritant/Hygroscopic
- safety_code
- 13-61-36/37-46
- Speicherklasse
- 13 - Non Combustible Solids
- Hazard Classifications
- Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralAquatic Chronic 3Eye Dam. 1
Chemie und Industrie
Pharmakologische Informationen
Verwendung und Herstellung
Uses
Used to make mustard oil, for printing and dyeing textiles, in photography (intensifier), and as a therapeutic hypotensive; [Merck Index] Used as a contact fungicide for green house vegetables and ornamentals and green house and open field strawberries; [ExPub: EFSA: DAR - Vol. 1]
Farming (Pesticides) [Category: Industry];Photographic Processing [Category: Other];Textiles (Printing, Dyeing, or Finishing) [Category: Industry]
Anwendungen
VerwendenPotassium Thiocyanate has been used as a catalyst in a one-pot reaction of dialkyl acetylenedicarboxylates with indane-1,3-dione. Potassium Thiocyanate has been used as a selective bacterial inhibitor to create ESS-3 broth to allow co-enrichment of the target pathogens and suppress growth of some non-target pathogens
Darstellung
synthetischePotassium thiocyanate may be made by adding caustic potash to a solution of ammonium thiocyanate, followed by evaporation of the solution. NH4SCN + KOH →KSCN + NH4OHAlso, the compound can be prepared by heating potassium cyanide with sulfur:KCN + S →KSCN.
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Ergänzende Hinweise
DefinitionChEBI: A potassium salt which is the monopotassium salt of thiocyanic acid.
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