Grundinformationen
- Standard-SMILES
CC(C)P(Cl)C(C)C- InChIKey
JZPDBTOWHLZQFC-UHFFFAOYSA-N- Summenformel
- C6H14ClP
- Durchschnittliche Molmasse
- 152,6 g/mol
- Monoisotopische Masse
- 152,0521651
Namen und Bezeichner
- Bevorzugter Name
- Chlorodiisopropylphosphine
- IUPAC
- chloro-di(propan-2-yl)phosphane
- Englischer Name
- Chlorodiisopropylphosphine
- Summenformel
- C6H14ClP
- Molmasse
- 152.6
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
40244-90-4- PubChem CID
- 538967
- DTXSID
DTXSID10337132- UNII
- 5FG5N54CYB
- EC Number
- 629-426-0
- Nikkaji
- J121.063G
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 2,3
- Polarare Oberfläche (TPSA)
- 0 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 0
- Frei drehbare Bindungen
- 2
- Schwere Atome
- 8
- Formalladung
- 0
- Komplexität
- 53
Physikochemische Eigenschaften
- Siedepunkt
- 69 °C33 · 69 °C33 mm Hg(lit.)
- Dichte
- 0.959 g/mL · 0.959 g/mL at 25 °C(lit.)
- Brechungsindex
- 20 · n20/D 1.475(lit.)
- Flammpunkt
- 39 °F · 39 °F
- storage temp.
- Refrigerator
- Aggregatzustand
- Liquid
- Farbe
- Clear light yellow
- InChI
- InChI=1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3
- InChIKey
- JZPDBTOWHLZQFC-UHFFFAOYSA-N
- SMILES
- P(C(C)C)(C(C)C)Cl
- CAS Datenbank
- 40244 · 40244-90-4(CAS DataBase Reference)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
Danger
H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids];H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 42 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
Gefahrenhinweise
Sicherheitsdaten
- wgk
- 3
- ridadr
- UN 2924 3/PG 2
- hs_code
- 29310099
- risk_code
- 11-34
- hazard_code
- F,C
- safety_code
- 16-26-27-36/37/39-45-1
- hazard_class
- 3.1
- packing_group
- II
- Speicherklasse
- 3 - Flammable liquids
- Hazard Classifications
- Flam. Liq. 2Skin Corr. 1B
Chemie und Industrie
Anwendungen
BeschreibungChlorodiisopropylphosphine is an organophosphorus compound of particular interest in synthetic chemistry, where it is used as a reagent in the preparation of phosphine ligands for transition metal complexes. Its utility in synthesising these complexes is due to the reactivity of the chloro group, which other groups can substitute to create a diverse array of ligands. This reactivity is also exploited in the study of catalysis, as the resulting phosphine ligands can be used to modulate the activity and selectivity of metal catalysts. In addition, Chlorodiisopropylphosphine is investigated for its potential in forming new organophosphorus compounds with applications in materials science. Researchers are also interested in the compound′s role in synthesising flame retardants, where its phosphorus content could contribute to the material′s flame-retarding properties.
VerwendenChlorodiisopropylphosphine can be used: To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.
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