Chlorodiisopropylphosphine

HCID 538967CAS 40244-90-4

Grundinformationen

Standard-SMILES
CC(C)P(Cl)C(C)C
InChIKey
JZPDBTOWHLZQFC-UHFFFAOYSA-N
Summenformel
C6H14ClP
Durchschnittliche Molmasse
152,6 g/mol
Monoisotopische Masse
152,0521651

Namen und Bezeichner

Bevorzugter Name
Chlorodiisopropylphosphine
IUPAC
chloro-di(propan-2-yl)phosphane
Englischer Name
Chlorodiisopropylphosphine
Summenformel
C6H14ClP
Molmasse
152.6

Namen und Synonyme

Chlorodiisopropylphosphine40244-90-45FG5N54CYBDTXSID10337132RefChem:575823DTXCID00288220629-426-0DiisopropylchlorophosphinePhosphinous chloride, bis(1-methylethyl)-chloro-di(propan-2-yl)phosphaneChlorobis(isopropyl)phosphineiPr2PCl
Weitere Namen anzeigen
Di-i-propyLAURORA KA-131898% (i-Pr)2PClCHLORODIISOPROPYLPHOSHINEbis-isopropylchlorophosphineCHLORODIISOPROPYLPHOSPHINE,96%
MFCD00015027ChlorodiiosopropylphosphineUNII-5FG5N54CYBP,P-Bis(1-methylethyl)phosphinous chloridePhosphinous chloride, P,P-bis(1-methylethyl)-Di-i-propylchlorophosphinedi-isopropylchlorophosphineC6H14ClP

Datenbank-Bezeichner

CAS
40244-90-4
PubChem CID
538967
DTXSID
DTXSID10337132
UNII
5FG5N54CYB
EC Number
629-426-0
Nikkaji
J121.063G

Eigenschaften

Berechnete Struktureigenschaften

XLogP
2,3
Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
2
Schwere Atome
8

Physikochemische Eigenschaften

Siedepunkt
69 °C33 · 69 °C33 mm Hg(lit.)
Dichte
0.959 g/mL · 0.959 g/mL at 25 °C(lit.)
Brechungsindex
20 · n20/D 1.475(lit.)
Flammpunkt
39 °F · 39 °F
storage temp.
Refrigerator
Aggregatzustand
Liquid

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids];H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Hazard Classes and CategoriesFlam. Liq. 2 (100%);Skin Corr. 1B (100%)

Sicherheitsdaten

wgk
3
ridadr
UN 2924 3/PG 2
hs_code
29310099
risk_code
11-34
hazard_code
F,C
safety_code
16-26-27-36/37/39-45-1

Chemie und Industrie

Anwendungen · 2 Einträge

BeschreibungChlorodiisopropylphosphine is an organophosphorus compound of particular interest in synthetic chemistry, where it is used as a reagent in the preparation of phosphine ligands for transition metal complexes. Its utility in synthesising these complexes is due to the reactivity of the chloro group, which other groups can substitute to create a diverse array of ligands. This reactivity is also exploited in the study of catalysis, as the resulting phosphine ligands can be used to modulate the activity and selectivity of metal catalysts. In addition, Chlorodiisopropylphosphine is investigated for its potential in forming new organophosphorus compounds with applications in materials science. Researchers are also interested in the compound′s role in synthesising flame retardants, where its phosphorus content could contribute to the material′s flame-retarding properties.

VerwendenChlorodiisopropylphosphine can be used: To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

Anbieter50 Anbieter

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
阿诺西(上海)生物技术有限公司400-1107768 15058188853 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
杭州鸿喜生物医药科技有限公司18989489206 · [email protected]
武汉欣扬瑞和化学科技有限公司13720274133 · [email protected]

Zugehörige Reaktionen

26

Verknüpfte Notizen

Wird geladen…