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Propyne, mixed with propadiene

HCID 62152
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Grundinformationen

CAS
59355-75-8
Standard-SMILES
C#CC.C=C=C
InChIKey
VBUBYMVULIMEHR-UHFFFAOYSA-N
Summenformel
C6H8
Durchschnittliche Molmasse
80,13 g/mol
Monoisotopische Masse
80,06260026

Namen und Bezeichner

Bevorzugter Name
Propyne, mixed with propadiene
IUPAC
propa-1,2-diene;prop-1-yne
Englischer Name
Methylacetylene and propadiene mixture,stabilized
Summenformel
C6H8
Molmasse
80.12772

Namen und Synonyme

59355-75-8Propadiene-methyl acetyleneMAPP gasRefChem:176562Methyl acetylene-propadiene mixture (ACGIH:OSHA)METHYL ACETYLENE-PROPADIENE MIXTURE (STABILIZED)MAPPUN1060propa-1,2-diene;prop-1-yneAllene PropynePropadien PropinSCHEMBL447120
Weitere Namen anzeigen
MAPDPROPYNE-ALLENEMIXTUREMethyl acetylene propadienePROPYL-ALLENEMIXTURE(MAPPGAS)Methyl acetylene propadiene mixture.Propyne and allene mixtures,stabilizedMethylacetylene and propadiene mixture,stabilized
56960-91-9

Datenbank-Bezeichner

CAS
59355-75-8
PubChem CID
62152

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
0
Schwere Atome
6
Formalladung
0
Komplexität
42

Experimentelle und physikochemische Eigenschaften

Density · 2 Einträge

0.576 at 59 °F

1.48(relative gas density)

SolubilityInsoluble
Flash PointNA (Gas)
Boiling Point · 2 Einträge

-36 to -4 °F

-36 to -4 °F

Melting Point · 2 Einträge

-213 °F

-213 °F

Vapor Density1.48
Odor ThresholdOdor Threshold Low: 100.0 [ppm];Reported odor threshold of 100 ppm
Vapor Pressure · 2 Einträge

>1 atm

>1 atm

Physical Description · 3 Einträge

Colorless gas with a strong, characteristic, foul odor. [Note: A fuel that is shipped as a liquefied compressed gas.]; [NIOSH]

Colorless gas with a strong, characteristic, foul odor.

Colorless gas with a strong, characteristic, foul odor. [Note: A fuel that is shipped as a liquefied compressed gas.]

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chemical: Methyl acetylene-propadiene mixture

MAPP: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationIMAP assessments - Methyl acetylene-propadiene mixture: Human health tier I assessment;IMAP assessments - Methyl acetylene-propadiene mixture: Environment tier I assessment
Hazards Summary · 1 Eintrag

Possible frostbite from contact with liquid; [NIOSH] MAPP gas is an explosive hazard. Reduce hazard by keeping concentrations below 10% of lower explosive limit (3400 ppm). It can cause anesthetic effects and at very high concentrations, asphyxiation. At an exposure level of 5000 ppm 7 hours/day, 5 days/week, experimental animals show decreased body weight. [ACGIH] Classified as Simple asphyxiant; [CAMEO] Methylacetylene-propadiene mixture, stabilized (UN1060) has warning of explosive polymerization; [ERG 2016] See Methylacetylene and Propadiene.

DOT ID and Guide1060 116P(stabilized)
Flammable LimitsFlammable Gas
Lower Explosive Limit (LEL) · 2 Einträge

3.4%

3.4%

Upper Explosive Limit (UEL) · 2 Einträge

10.8%

10.8%

Hazardous Reactivities and IncompatibilitiesStrong oxidizers, copper alloys [Note: Forms explosive compounds at high pressure in contact with alloys containing more than 67% copper.]

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Used as fuel for industrial cutting; [ACGIH]

Gas Welding and Cutting [Category: Weld]

Anwendungen

VerwendenIndustrial fuel gas for cutting, welding, brazing, heat treating, and metallizing.

Zugehörige Reaktionen

3
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 372366
HRID 372366als Eduktuspto-grants-1978_05
Reaktionsgleichung von HRID 443996
HRID 443996als Eduktuspto-grants-1981_04
Reaktionsgleichung von HRID 1289263
HRID 1289263als Eduktuspto-grants-1998_05

Notizen zur Verbindung

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Physikochemische Eigenschaften

EPA chemische Informationen
MAPP (59355-75-8)

Sicherheit und Schutzausrüstung

First Aid · 1 Eintrag

(General first aid procedures);Eye: Frostbite - If eye tissue is frozen, seek medical attention immediately; if tissue is not frozen, immediately and thoroughly flush the eyes with large amounts of water for at least 15 minutes, occasionally lifting the lower and upper eyelids. If irritation, pain, swelling, lacrimation, or photophobia persist, get medical attention as soon as possible.;Skin: Frostbite - Compressed gases may create low temperatures when they expand rapidly. Leaks and uses that allow rapid expansion may cause a frostbite hazard. Wear appropriate personal protective clothing to prevent the skin from becoming frozen.;Breathing: Respiratory support

Respirator Recommendations · 1 Eintrag

NIOSH/OSHA;Up to 3400 ppm:;(APF = 10) Any supplied-air respirator;(APF = 50) Any self-contained breathing apparatus with a full facepiece;Emergency or planned entry into unknown concentrations or IDLH conditions:;(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode;(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus;Escape:;(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern;Any appropriate escape-type, self-contained breathing apparatus;Important additional information about respirator selection

Threshold Limit Values (TLV) · 4 Einträge

1000.0 [ppm]

1250.0 [ppm]

1000 ppm [1964]

1250 ppm [1964]

Permissible Exposure Limit (PEL) · 3 Einträge

1000.0 [ppm]

1000 ppm (1800 mg/m³)

TWA 1000 ppm (1800 mg/m3) See Appendix G

Protective Action Criteria (PAC) · 3 Einträge

1250 [ppm]

2500 [ppm]

15000 [ppm]

Recommended Exposure Limit (REL) · 3 Einträge

1000 ppm (1800 mg/m³)

1250 ppm (2250 mg/m³)

TWA 1000 ppm (1800 mg/m3) ST 1250 ppm (2250 mg/m3)

Immediately Dangerous to Life or Health (IDLH) · 3 Einträge

3400.0 [ppm];Excerpts from Documentation for IDLHs: Basis for revised IDLH: Since a methyl acetylene­propadiene mixture appears to have relatively low toxicity, and based on an analogy to methyl acetylene [ACGIH 1991], the revised IDLH is 3,400 ppm based strictly on safety considerations (i.e., being 10% of the lower explosive limit of 3.4%).

3400 ppm

3400 ppm [10%LEL];See: 59355758

Toxikologische Informationen

Target Organsrespiratory system, central nervous system
Adverse EffectsNeurotoxin - Acute solvent syndrome;Other Poison - Simple Asphyxiant
Exposure Routesinhalation, skin and/or eye contact (liquid)
Signs and Symptomsirritation respiratory system; excitement, confusion, anesthesia; liquid: frostbite

Regulatorische Informationen

Regulatory Information · 2 Einträge

Chemical: Methyl acetylene-propadiene mixture

MAPP: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Sicherheitsdaten

OEB
A
OEL
TWA: 1000 ppm (1800 mg/m3), STEL: 1250 ppm (2250 mg/m3)
IDLA
3,400 ppm [10% LEL]