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Ferrous sulfate heptahydrate

HCID 62662
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Grundinformationen

CAS
15491-23-3
Standard-SMILES
O.O.O.O.O.O.O.O=S(=O)([O-])[O-].[Fe+2]
InChIKey
SURQXAFEQWPFPV-UHFFFAOYSA-L
Summenformel
FeH14O11S
Durchschnittliche Molmasse
278,02 g/mol
Monoisotopische Masse
277,96061977

Überblick

Iron(2+) sulfate heptahydrate is a hydrate that is the heptahydrate form of iron(2+) sulfate. It is used as a source of iron in the treatment of iron-deficiency anaemia (generally in liquid-dosage treatments; for solid-dosage treatments, the monohydrate is normally used). It has a role as a nutraceutical, a reducing agent and an anti-anaemic agent. It is an iron molecular entity and a hydrate. It contains an iron(2+) sulfate (anhydrous).

Namen und Bezeichner

Bevorzugter Name
Ferrous sulfate heptahydrate
IUPAC
iron(2+);sulfate;heptahydrate
Englischer Name
Ferrous sulfate heptahydrate
Summenformel
FeH14O11S
Molmasse
278.01

Namen und Synonyme

7782-63-0Iron(II) sulfate heptahydrateFERROUS SULFATE HEPTAHYDRATEIron(2+) sulfate heptahydrateIron sulfate heptahydrateMelanterite mineralFesotymeIrosulSiderotil mineralTauriscite mineralSzomolnikite mineralFerrous sulfate, heptahydrate
Weitere Namen anzeigen
FERROINsulfate heptahydrateFERROIN INDICATOR SOLUTIONIron(Ⅱ) sulfate heptahydrateFERROIN INDICATORFerrous sulfate heptferrous sulfate granularFerrousSulphateMonohydrateIron(II)sulphateheptahydrate,98%
Iron(II) sulfate (1:1), heptahydrateTetucur-SDTXSID9040344CHEBI:75836RefChem:921576DTXCID7020344616-510-7Melanterite

Datenbank-Bezeichner

CAS
15491-23-3、7782-63-0

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
95,6 Ų
H-Brücken-Donoren
7
H-Brücken-Akzeptoren
11
Frei drehbare Bindungen
0
Schwere Atome
13
Formalladung
0
Komplexität
62,2

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metals, Inorganic Compounds
Density1.895 @25 °C
Physical Description · 2 Einträge

CBI

Blue-green odorless solid; Efflorescent in dry air; Soluble in water; [Merck Index] Green crystalline solid; [Alfa Aesar MSDS]

Physikochemische Eigenschaften

Schmelzpunkt
64 °C · 64 °C
Dichte
1.898 g/mL · 1.898 g/mL at 25 °C (lit.)
Dampfdruck
14.6 mm · 14.6 mm Hg ( 25 °C)
storage temp.
15 °C · Store at +15°C to +25°C.
Löslichkeit
25.6 g/100 · 25.6 g/100 mL (20°C)
Aggregatzustand
Solution
Wichte
1.898 · 1.898
Farbe
Slightly greenish to blue
Geruch (Odor)
pale bluish-grn. cryst. or gran., odorless

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

Warning

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P264, P264+P265, P270, P280, P301+P317, P302+P352, P305+P351+P338, P321, P330, P332+P317, P337+P317, P362+P364, and P501 (click each P-code to see the statement)

This chemical does not meet GHS hazard criteria for < 0.1% (2 of 2619) of reports.

Warning

H302 (> 99.9%): Harmful if swallowed [Warning Acute toxicity, oral]

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: Sulfuric acid, iron(2+) salt (1:1), heptahydrate

Regulation (EC) No 1831/2003 (amended)

Sulfuric acid, iron(2+) salt (1:1), heptahydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, iron(2+) salt (1:1), heptahydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Ferrous sulphate, heptahydrate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Sulfuric acid, iron(2+) salt (1:1), heptahydrate: Human health tier I assessment
Hazards Summary · 1 Eintrag

A skin, eye, and mucous membrane irritant; May cause gastrointestinal disturbances, shock, cyanosis, coma, and liver damage; [Merck Index] A skin and strong eye irritant; Harmful by ingestion; [Alfa Aesar MSDS] See Ferrous sulfate. See Iron salts, soluble.

Hazard Classes and Categories · 4 Einträge

Acute Tox. 4 (> 99.9%)

Acute toxicity - category 4

Acute toxicity (Oral) - Category 4

Chemie und Industrie

Verwendung und Herstellung

Uses · 3 Einträge

Used in iron electroplating baths, fertilizers, pesticides, radiation dosimeters, writing ink, process engraving, lithography, dyeing leather, etching aluminum, water treatment, brown ring test for nitrates, and food and feed supplements; Also used as a reducing agent, wood preservative, weed killer, polymerization catalyst, plant food, and hematinic; [Merck Index] Formerly registered in the US as a moss killer/fertilizer for lawns; [NPIRS] Used as a nutritional supplement, processing aid, and stabilizer or thickener for foods; [FDA]

Aluminum Producing [Category: Industry]

Lithography printing [Category: Hobbies]

U.S. Production2023: 75,000 - <500,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesSoil amendments (fertilizers)
Household ProductsInformation on 27 consumer products that contain Ferrous sulfate heptahydrate in the following categories is provided:
General Manufacturing InformationPesticide, Fertilizer, and Other Agricultural Chemical Manufacturing
Anwendungen · 2 Einträge

Beschreibung§184.1315(a) Ferrous sulfate heptahydrate (iron (II) sulfate heptahydrate, FeS04-7H2O) is prepared by the action of sulfuric acid on iron. It occurs as pale, blueish-green crystals or granules. Progressive heating of ferrous sulfate heptahydrate produces ferrous sulfate (dried). Ferrous sulfate (dried) consists primarily of ferrous sulfate monohydrate (CAS No. 17375-41-6) with varying amounts of ferrous sulfate tetrahydrate (CAS No. 20908-72-9) and occurs as a grayish-white to buff-colored powder.

VerwendenUsed in quantitative analysis of nitrates .

Vor- und nachgelagerte Produkte

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PubChem CID
62662
DTXSID
DTXSID9040344
ChEBI
CHEBI:75836
UNII
39R4TAN1VT
EC Number
616-510-7
PH
3 · 3.0-4.0 (25℃, 50mg/mL in H2O)
Wasserlöslichkeit
25.6 g/100 · 25.6 g/100 mL (20 ºC)
Merck
14 · 14,4057
Stabilität
Stable. Substances to be avoided include strong oxidizing agents. Air and moisture sensitive.
InChI
1S/Fe.H2O4S.7H2O/c;1-5(2,3)4;;;;;;;/h;(H2,1,2,3,4);7*1H2/q+2;;;;;;;;/p-2
InChIKey
SURQXAFEQWPFPV-UHFFFAOYSA-L
SMILES
[Fe+2].[S](=O)(=O)([O-])[O-].O.O.O.O.O.O.O
LogP
-1.031 · -1.031 (est)
CAS Datenbank
7782 · 7782-63-0(CAS DataBase Reference)
EPA chemische Informationen
Ferrous sulfate heptahydrate (7782-63-0)

Acute Tox. 4 *

Sicherheit und Schutzausrüstung

Threshold Limit Values (TLV)1.0 [mg/m3], as Fe (soluble iron salts)
Protective Action Criteria (PAC) · 3 Einträge

2.5 [mg/m3]

27 [mg/m3]

160 [mg/m3]

Toxikologische Informationen

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.

Sicherheitsdaten

F
10-23
wgk
1
tsca
Yes
ridadr
UN3077
hs_code
28332950
RTECS-Nr.
NO8510000
risk_code
22-36/38
Toxizität
LD50 in mice: 65 mg/kg i.v.; 1.52 g/kg orally (Hoppe)
hazard_code
Xn
safety_code
36/37/39-46
hazard_class
9
Speicherklasse
11 - Combustible Solids
Hazard Classifications
Acute Tox. 4 OralEye Irrit. 2Skin Irrit. 2

Vorgelagerte Rohstoffe

Sulfuric acid iron(2+) salt monohydrateIron filingsIronmetal,wire0.075mm(0.003in)diaspectro99.9,metalsbasisRutil (TiO2)EisenILMENITESchwefelsure

Nachgelagerte Produkte

Iron Oxide GreenMethyl 6-quinolineacetateCitronellolEisendilactat8-Chlorchinolin6-Chloroindole-2-carboxylic acidNaphthenate drier6-Quinolinylmethanol5-Chlorindolferrous pyrophosphate for foodPOTASSIUM FERRATE(VI)Eisen(II)fumaratEisenoxidFERROUS GLUCONATE DIHYDRATEFoliar-fertilizerTetrakaliumhexacyanoferrat4-Amino-3-fluoropyridineTitandihydroxidoxidPreussisch BlauGestodenethybenzene dehydrogenation catayst NCY4-FluoroindoleAnatas (TiO2)medium temperature Shift catalystsDiammoniumeisenbis(sulfat)Manganese sulfate monohydrateFE2O3 AS BROWN PIGMENTPigment Blue 27TetranatriumhexacyanoferratPolyferric sulfateTrieisentetraoxidEisenorthophosphatPotassium ferrocyanide trihyrateNaphthensuren, EisensalzeEisenoxidbraunCI 77492Eisenhydroxidoxidgelbmedium(high)temperature Shift catalystsAmmoniumeisen(III)citratMagnetit
Ergänzende Hinweise · 1 Eintrag

DefinitionChEBI: A hydrate that is the heptahydrate form of iron(2+) sulfate. It is used as a source of iron in the treatment of iron-deficiency anaemia (generally in liquid-dosage treatments; for solid-dosage treatments, the monohydrate is normally used).