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Diammoniumhexachloropalladat

Diammonium hexachloropalladate

HCID 62732
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Grundinformationen

CAS
19168-23-1
Standard-SMILES
[Cl][Pd-2]([Cl])([Cl])([Cl])([Cl])[Cl].[NH4+].[NH4+]
InChIKey
LOLIPEAFAJNGJM-UHFFFAOYSA-J
Summenformel
Cl6Pd.2H4N
Durchschnittliche Molmasse
355,2 g/mol
Monoisotopische Masse
351,78534

Überblick

Ammonium hexachloropalladate is a salt comprising separate ammonium cations and octahedral [PdCl6]2 anions. It contains a hexachloropalladate(2-).

Namen und Bezeichner

Bevorzugter Name
Diammonium hexachloropalladate
IUPAC
diazanium;hexachloropalladium(2-)
Lokaler Name
Diammoniumhexachloropalladat
Englischer Name
Ammonium hexachloropalladate(IV)
Summenformel
Cl6H4NPd-
Molmasse
337.16

Namen und Synonyme

Ammonium hexachloropalladateDiammonium hexachloropalladateDiammonium hexachloropalladate(2-)CCRIS 7829EINECS 242-854-9CHEBI:60124Palladate(2-), hexachloro-, diammonium, (OC-6-11)-Palladate(2-), hexachloro-, ammonium (1:2), (OC-6-11)-ammonium hexachloridopalladate(IV)ammonium hexachloridopalladate(2-)RefChem:586257242-854-9
Weitere Namen anzeigen
hexachloropalladium(2-)99.9%(metalsbasis),Pd30%PALLADIC AMMONIUM CHLORIDEAmmonium palladic chlorideAmmoniumchloropalladate(IV)ammoniumhexachloropalladateDiazanium hexachloropalladiumPalladium(IV)-ammonium chloride
Ammonium hexachloropalladate(IV)19168-23-1MFCD00015959Diammonium palladium hexachloride13820-55-8Hexachloropalladate(2-) diammoniumPalladate(2-), hexachloro-, diammoniumAmmonium chloropalladate ((NH4)2PdCl6)

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
2 Ų
H-Brücken-Donoren
2
H-Brücken-Akzeptoren
1
Frei drehbare Bindungen
0
Schwere Atome
9
Formalladung
0
Komplexität
62,7

Experimentelle und physikochemische Eigenschaften

Physical DescriptionWet Solid

Physikochemische Eigenschaften

Schmelzpunkt
°Cd ec.)
Dichte
2 · 2,418 g/cm3
Dampfdruck
0 Pa · 0Pa at 20℃
storage temp.
2 · under inert gas (nitrogen or Argon) at 2-8°C
Aggregatzustand
Crystalline
Farbe
Red-orange
Wichte
2.418 · 2.418
Wasserlöslichkeit
slightly soluble
Stabilität
hygroscopic
InChI
1S/6ClH.2H3N.Pd/h6*1H;2*1H3;/q;;;;;;;;+4/p-4
InChIKey
LOLIPEAFAJNGJM-UHFFFAOYSA-J
SMILES
[NH4+].[NH4+].Cl[Pd--](Cl)(Cl)(Cl)(Cl)Cl
CAS Datenbank
19168 · 19168-23-1(CAS DataBase Reference)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H301 (68.9%): Toxic if swallowed [Danger Acute toxicity, oral]

P261, P264, P264+P265, P270, P272, P273, P280, P301+P316, P301+P317, P302+P352, P305+P351+P338, P305+P354+P338, P317, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 151 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: Palladate(2-), hexachloro-, diammonium, (OC-6-11)-

Palladate(2-), hexachloro-, ammonium (1:2), (OC-6-11)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Palladate(2-), hexachloro-, ammonium (1:2), (OC-6-11)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Diammonium hexachloropalladate (EC: 242-854-9)

Restricted substance: Diammonium hexachloropalladate

Other Safety InformationIMAP assessments - Palladate(2-), hexachloro-, diammonium, (OC-6-11)-: Human health tier I assessment
Hazard Classes and CategoriesAcute Tox. 3 (68.9%)

Toxikologische Informationen

Treatment · 2 Einträge

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Chemie und Industrie

Pharmakologische Informationen

Metabolism/Metabolites · 2 Einträge

Palladium may be absorbed through oral, dermal, and inhalation exposure. Once in the body it distributes to the kidney, liver, spleen, lymph nodes, adrenal gland, lung and bone. Palladium's ability to form complexes allows it the bind to amino acids, proteins, DNA, and other macromolecules. Palladium and its metabolites are excreted in the urine and faeces. (A21)

Palladium may be absorbed through oral, dermal, and inhalation exposure. Once in the body it distributes to the kidney, liver, spleen, lymph nodes, adrenal gland, lung and bone. Palladium's ability to form complexes allows it the bind to amino acids, proteins, DNA, and other macromolecules. Palladium and its metabolites are excreted in the urine and faeces. (A21)

Verwendung und Herstellung

U.S. Production2023: 75,000 - <500,000 lb
Industry UsesIntermediate
General Manufacturing Information · 2 Einträge

All Other Basic Inorganic Chemical Manufacturing

Palladate(2-), hexachloro-, ammonium (1:2), (OC-6-11)-: ACTIVE

Anwendungen · 1 Eintrag

VerwendenAmmonium hexachloropalladate(IV) is used as analytical reagent and as a catalyst in the chemical synthesis. It is also used as raw material and intermediates in organic synthesis and pharmaceutical field. Further, it is used in emission spectrographic analysis.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

Ammoniumchlorid

Zugehörige Reaktionen

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Reaktionsgleichung von HRID 1413031
HRID 1413031als Eduktuspto-grants-1981_02

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Datenbank-Bezeichner

CAS
19168-23-1
PubChem CID
62732
ChEBI
CHEBI:60124
EC Number
242-854-9
EPA chemische Informationen
Palladate(2-), hexachloro-, diammonium, (OC-6-11)- (19168-23-1)

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 2 Einträge

Contact with palladium may cause palladium sensitivity and allergy. Animal studies have shown that palladium may damage the liver and kidney. (L798)

Contact with palladium may cause palladium sensitivity and allergy. Animal studies have shown that palladium may damage the liver and kidney. (L798)

Toxicity Summary · 2 Einträge

Due to their ability to form strong complexes with both inorganic and organic ligands, palladium ions can disturb cellular equilibria, replace other essential ions, and interact with functional groups of macromolecules, such as proteins or DNA. Palladium complexes binding to DNA and RNA leads to strand breakage. Palladium ions are able to inhibit most major cellular functions, including DNA and RNA synthesis. Palladium compounds have been shown to bind to and inhibit various enzymes, including creatine kinase and prolyl hydroxylase. (L798)

Due to their ability to form strong complexes with both inorganic and organic ligands, palladium ions can disturb cellular equilibria, replace other essential ions, and interact with functional groups of macromolecules, such as proteins or DNA. Palladium complexes binding to DNA and RNA leads to strand breakage. Palladium ions are able to inhibit most major cellular functions, including DNA and RNA synthesis. Palladium compounds have been shown to bind to and inhibit various enzymes, including creatine kinase and prolyl hydroxylase. (L798)

Signs and Symptoms · 2 Einträge

Skin contact with palladium may cause contact dermatitis, erythema, and oedema. (L798)

Skin contact with palladium may cause contact dermatitis, erythema, and oedema. (L798)

Carcinogen Classification · 2 Einträge

No indication of carcinogenicity to humans (not listed by IARC).

No indication of carcinogenicity to humans (not listed by IARC).

Sicherheitsdaten

wgk
3
tsca
TSCA listed
ridadr
3288
RTECS-Nr.
BP5390000
risk_code
22-36/38-36/37/38
Toxizität
skn-rbt 100 mg/24H SEV AEHLAU 30,168,75
hazard_code
Xn,Xi
safety_code
26-36-37/39
hazard_class
6.1(b)
packing_group
III
Speicherklasse
11 - Combustible Solids
Hazard Classifications
Acute Tox. 4 OralEye Irrit. 2Skin Irrit. 2