Diphenylphosphinchlorid

Diphenylphosphinic chloride

HCID 73910CAS 1499-21-4

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Grundinformationen

Standard-SMILES: O=P(Cl)(c1ccccc1)c1ccccc1
InChIKey: QPQGTZMAQRXCJW-UHFFFAOYSA-N
Summenformel: C12H10ClOP
Durchschnittliche Molmasse: 236,63 g/mol
Monoisotopische Masse: 236,01577925

Namen und Bezeichner

Bevorzugter Name: Diphenylphosphinic chloride
IUPAC: [chloro(phenyl)phosphoryl]benzene
Lokaler Name: Diphenylphosphinchlorid
Englischer Name: Diphenylphosphinic Chloride
Summenformel: C12H10ClOP
Molmasse: 236.63

Namen und Synonyme

Diphenylphosphinic chloride1499-21-4Diphenylphosphinyl chlorideChlorodiphenylphosphine oxidePhosphinic chloride, diphenyl-diphenylphosphinoyl chloridePhosphinic chloride, P,P-diphenyl-Diphenylchlorophosphine oxideDiphenylphosphorus oxychloridediphenylphosphinic acid chloride5GP30GY04VEINECS 216-107-2

Weitere Namen anzeigen

DPPCDPP-CLPh2POClphosphinic chLDiphenylphoshinic

NSC-175848DIPHENYLPHOSPHONIC CHLORIDEDTXSID50164424NSC 175848RefChem:588942DTXCID6086915216-107-2[chloro(phenyl)phosphoryl]benzene

Datenbank-Bezeichner

CAS: 1499-21-4
PubChem CID: 73910
DTXSID: DTXSID50164424
UNII: 5GP30GY04V
EC Number: 216-107-2
Nikkaji: J150.122D

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 2,1
Polarare Oberfläche (TPSA): 17,1 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 1
Frei drehbare Bindungen: 2
Schwere Atome: 15
Formalladung: 0
Komplexität: 220

Experimentelle und physikochemische Eigenschaften

SpringerMaterials PropertiesNuclear quadrupole resonance spectroscopy

Physikochemische Eigenschaften

Schmelzpunkt: 20 °C · 20°C
Siedepunkt: 222 °C/16 · 222 °C/16 mmHg (lit.)
Dichte: 1.24 g/mL · 1.24 g/mL at 25 °C (lit.)
Brechungsindex: 20 · n20/D 1.609(lit.)
Flammpunkt: 79 °F · 79 °F
storage temp.: 2 · 2-8°C
Löslichkeit: soluble in Chloroform, methanol
Aggregatzustand: Liquid
Wichte: 1.24 · 1.24
Farbe: Clear colorless to yellow
Wasserlöslichkeit: decomposes
BRN: 975191 · 975191
InChI: 1S/C12H10ClOP/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChIKey: QPQGTZMAQRXCJW-UHFFFAOYSA-N
SMILES: ClP(=O)(c1ccccc1)c2ccccc2
CAS Datenbank: 1499 · 1499-21-4(CAS DataBase Reference)
NIST chemische Informationen: Diphenylphosphinic chloride(1499-21-4)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

This chemical does not meet GHS hazard criteria for 1.4% (1 of 71) of reports.

Danger

H226 (71.8%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P319, P321, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 71 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Status: Active Update: 31-01-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/27651

Diphenylphosphinic chloride: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 3 (71.8%)

Sicherheitsdaten

F: 10-21
wgk: 3
ridadr: UN 2920 8/PG 2
hs_code: 29310095
risk_code: 10-34
hazard_code: C,F
hazard_note: Flammable/Corrosive
safety_code: 16-26-36/37/39-45
hazard_class: 8
packing_group: II
Speicherklasse: 3 - Flammable liquids
Hazard Classifications: Eye Dam. 1Flam. Liq. 3Skin Corr. 1BSkin Sens. 1A

Chemie und Industrie

Anwendungen

VerwendenDiphenylphosphinic chloride (Ph2POCl) is widely used as a precursor to synthesize various chiral phosphine bidentate ligands for asymmetric synthesis, in addition to several peptide coupling agents.