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Styrol

Styrene

HCID 7501
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Grundinformationen

CAS
100-42-5
Standard-SMILES
C=Cc1ccccc1
InChIKey
PPBRXRYQALVLMV-UHFFFAOYSA-N
Summenformel
C8H8
Durchschnittliche Molmasse
104,15 g/mol
Monoisotopische Masse
104,06260026

Namen und Bezeichner

Bevorzugter Name
Styrene
IUPAC
styrene
Lokaler Name
Styrol
Englischer Name
Styrene
Summenformel
C8H8
Molmasse
104.15

Namen und Synonyme

STYRENE100-42-5EthenylbenzenePhenylethyleneVinylbenzeneStyrolBenzene, ethenyl-CinnameneStyrene monomerPhenyletheneStyrolenePhenethylene
Weitere Namen anzeigen
SMOligosaccharidemethyl 2-methylprop-2-enoate
VinylbenzolStyroleVinyl benzeneStyropol SOCinnamolStyrenBenzene, vinyl-Cinnamenol

Datenbank-Bezeichner

CAS
100-42-5、79637-11-9、98444-30-5
PubChem CID
7501
DTXSID
DTXSID2021284
ChEMBL
CHEMBL285235
ChEBI
CHEBI:27452
UNII
44LJ2U959V
EC Number
202-851-5、616-714-6、619-344-3
Nikkaji
J4.006A

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

XLogP
2,9
Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
1
Schwere Atome
8
Formalladung
0
Komplexität
68

Physikochemische Eigenschaften

Schmelzpunkt
30 °C · −30 °C (−22 °F; 243 K)
Siedepunkt
145 °C · 145 °C (293 °F; 418 K)
Dichte
0.909 g/cm3 · 0.909 g/cm3
Dampfdichte
3.6 · 3.6 (vs air)
Dampfdruck
12.4 mm · 12.4 mm Hg ( 37.7 °C)
Brechungsindex
1.5469 · 1.5469
Flammpunkt
31 °C · 31 °C (88 °F; 304 K)
storage temp.
20 °C · Store at <= 20°C.
Löslichkeit
0.24 g/l · 0.24g/l
pka
14 · >14 (Schwarzenbach et al., 1993)
Aggregatzustand
oily liquid
Farbe
colorless
Wichte
0.909 · 0.909
Geruch (Odor)
0.1 % · at 0.10 % in triacetin. sweet balsam floral plastic
Geruchsart
balsamic

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

Sicherheitsdaten

OEB
A
OEL
TWA: 50 ppm (215 mg/m3), STEL: 100 ppm (425 mg/m3)
wgk
2
IDLA
700 ppm
tsca
TSCA listed
ridadr
UN 2055 (STYRENE MONOMER, STABILIZED)
hs_code
2902 50 00
RTECS-Nr.
WL3675000
risk_code
10-20-36/38-40-36/37/38-39/23/24/25-23/24/25-11-48/20-63
Toxizität
LD50 in mice (mg/kg): 660 ± 44.3 i.p.; 90 ± 5.2 i.v.
hazard_code
Xn,T,F
safety_code
23-36-26-16-45-36/37-7-46
hazard_class
3
packing_group
III
Speicherklasse
3 - Flammable liquids
Giftige Stoffe Daten
100-42-5(Hazardous Substances Data)
Hazard Classifications
Acute Tox. 4 InhalationAquatic Chronic 3Asp. Tox. 1Eye Irrit. 2Flam. Liq. 3Repr. 2Skin Irrit. 2STOT RE 1 InhalationSTOT SE 3
Selbstentzündungstemperatur
914 °F

Chemie und Industrie

Anwendungen · 3 Einträge

BeschreibungStyrene has a characteristic, sweet, balsamic, almost floral odor that is extremely penetrating. Styrene occurs naturally in plants. It was first isolated from a resin called storax obtained from the inner bark of the Oriental sweet gum tree (Liquidambar orientalis) by Bonastre. In 1839, the German apothecary Eduard Simon prepared styrene by distilling it from storax and called it styrol. Simon observed it solidifi ed into a rubbery substance after being stored and believed it had oxidized into styrol oxide. Subsequent analysis showed the solid did not contain oxygen and it was renamed metastyrol. This was the first written record of polymerization in chemistry. In 1845, the English chemist, John Blyth, and the German chemist, August Wilhelm von Hofmann (1818 1892), observed that styrene was converted to polystyrene by sunlight and that styrene could be polymerized to polystyrene by heating in the absence of oxygen. It took another 70 years for the polymerization of styrene to be described by Hermann Staudinger (1881 1965) in the 1920s. This laid the foundation for the commercial polystyrene industry that developed in the 1930s.

OccurrenceReported found in cranberry and bilberry, currants, grape, parsley, milk and dairy products, whiskey, cocoa, coffee, tea, roasted filberts and roasted peanuts. Also reported found in fresh apple, guava fruit, pineapple, vinegar, butter, fish oil, black tea, roasted filbert, roasted peanut, soybean, plum brandy, apple brandy, Brazil nut, rice bran, Bourbon vanilla, grapes, peach, strawberry, onion, peas, bell pepper, cassia leaf, cheeses, parsley, milk, boiled and scrambled egg, lean fish, fish oil, cooked chicken and beef, rum, malt and Scotch whiskey, cider, grape, wine, cocoa, coffee, honey, cloudberry, plum, rose apple, beans, trassi, walnut, buckwheat, soursop, watercress, kiwifruit, wild rice, sapodilla fruit, nectarine, okra, crab, crayfish and pawpaw.

VerwendenStyrene (monomer) is a viscous, highly flammable liquid that evaporates easily and polymerizes readily to polystyrene unless a stabilizer is added. Styrene is used in multiple industries, especially in reinforced plastics (e.g., fiberglass boats), and is widely used to make plastics and rubber, packaging materials (e.g., packing peanuts ), insulation for buildings, plastic pipes, food containers (e.g., takeout containers), and carpet backing) (ATSDR, 2010).

Darstellung

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Biologische Quelle
synthetic
Explosionsgrenze
1.1 · 1.1-8.9%(V)
Odor Threshold
0.035 ppm · 0.035ppm
Wasserlöslichkeit
0.3 g/L · 0.3 g/L (20 ºC)
Spezifische Wärmekapazität
1.75 J/ · Cp(liquid): 1.75 J/(g·K), at 25℃
Merck
14 · 14,8860
BRN
1071236 · 1071236
Henry's Law Constant
(x 10-3 atmm3/mol): 3.91 at 25 °C (static headspace-GC, Welke et al., 1998)
Dielectric constant
2.4 · 2.4(25℃)
Stabilität
Stable, but may polymerize upon exposure to light. Normally shipped with a dissolved inhibitor. Substances to be avoided include strong acids, aluminium chloride, strong oxidizing agents, copper, copper alloys, metallic salts, polymerization catalysts and accelerators. Flammable - vapour may travel considerable distance to ignition source
Major Application
environmental
Kosmetik-Inhaltsstoffe Funktionen
SOLVENT
InChI
1S/C8H8/c1-2-8-6-4-3-5-7-8/h2-7H,1H2
InChIKey
PPBRXRYQALVLMV-UHFFFAOYSA-N
SMILES
C=Cc1ccccc1
LogP
2.96 at · 2.96 at 25℃
CAS Datenbank
100 · 100-42-5(CAS DataBase Reference)
NIST chemische Informationen
Styrene(100-42-5)
EPA chemische Informationen
Styrene (100-42-5)

synthetischePrepared from ethylbenzene or from phenylethanol.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

PlatinDieisentrioxidBenzolPoly(acrylic acid)

Nachgelagerte Produkte

modified acrylic resin emulsion SBCross-linking agentCarboxy styrene-butadiene latexStyrene-acrylic latex paint for exterior wallAdhesive for nonwoven fabricsulfonic ion exchange membrane based on polypropylene/poly (ST-DVB)Phenylethan-1,2-diolLeather lustering agentAcrylic latexhigh-temperature leveling agent FZ-802Methyl a yclopentylmandelate1-Methyl-3-(a-cyclopentylmandeloyloxy)pyrrolidinehydrochloride(2-Chlor-1-ethoxyethyl)benzolAnion exchange resin,strong basic styreneBrominated polystyreneBromadiolonPolystyreneGlass fiber reinforced plastic cooling towera new kind of liquid crystal copolymerPhenyloxiranSorbitan1-(a-Ethoxyphenethyl)piperazine">pesticide emulsifier 1900^THERMOPLASTIC ACRYLIC RESINHigh temperature levelling agent BOFAntioxidant AMSilicone acrylic resinnuclear grade ion exchange resin 9094,4'-Diamino-diphenyl-methanStyrene-acrylic latexBinder for coating printingBT modified acrylic resin binder seriesMethyl-(3-phenyl-propyl)-amineSilicone acrylic emulsionPesticide emulsifierConstruction emulsion BC-01MethylbenzoylformiatChlortrianisen(3-Chlorprop-1-enyl)benzol4,4`-di(a-methylbenzyl)diphenylamine

Ergänzende Hinweise

DefinitionChEBI: A vinylarene that is benzene carrying a vinyl group. It has been isolated from the benzoin resin produced by Styrax species.