Diisopropylazodicarboxylat

Diisopropyl diazene-1,2-dicarboxylate

HCID 75555CAS 2446-83-5

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Grundinformationen

Standard-SMILES: CC(C)OC(=O)N=NC(=O)OC(C)C
InChIKey: VVWRJUBEIPHGQF-UHFFFAOYSA-N
Summenformel: C8H14N2O4
Durchschnittliche Molmasse: 202,21 g/mol
Monoisotopische Masse: 202,09535693

Namen und Bezeichner

Bevorzugter Name: Diisopropyl diazene-1,2-dicarboxylate
IUPAC: propan-2-yl N-propan-2-yloxycarbonyliminocarbamate
Lokaler Name: Diisopropylazodicarboxylat
Englischer Name: Diisopropyl azodicarboxylate
Summenformel: C8H14N2O4
Molmasse: 202.21

Namen und Synonyme

DIADDiisopropyl diazene-1,2-dicarboxylateAzodicarboxylic Acid Diisopropyl EsterDiisopropyl (E)-diazene-1,2-dicarboxylateDiisopropyl (E)-1,2-diazenedicarboxylate(E)-diisopropyl diazene-1,2-dicarboxylateisopropyl N-isopropoxycarbonyliminocarbamate1,2-Diazenedicarboxylic Acid 1,2-Bis(1-methylethyl) Ester; Azodiformic Acid Diisopropyl Ester; DIAD; Diisopropyl Azodiformate; Diisopropyl diazodicarboxylate;diisopropylazocarboxylateisopropyl (NE)-N-isopropoxycarbonyliminocarbamateisopropyl (NZ)-N-isopropoxycarbonyliminocarbamatediisopropyazodicarboxylate

Weitere Namen anzeigen

diisopropyl azodiformateDisopropyl AzodicarboxylateAZODICARBONIC ACID DIISOPROPYL ESTERDiisopropyl azodicarboxylate [DIAD]Propan-2-yl N-propan-2-yloxycarbonyliminocarbamateDIAD(Diisopropylazodicarboxylate)

diisopropylazodicaroxylatediisoproylazodicarboxylateDiisopyl azodicarboxylateDiisopropylazodicarboxlatediisopropyl azocarboxylatediisoproyl azodicaroxylatediisopropyl azodicaboxylatediisopropyl azodicaroxylate

Datenbank-Bezeichner

CAS: 2446-83-5
PubChem CID: 75555

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 2,6
Polarare Oberfläche (TPSA): 77,3 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 4
Frei drehbare Bindungen: 4
Schwere Atome: 14
Formalladung: 0
Komplexität: 211

Physikochemische Eigenschaften

Schmelzpunkt: 3 · 3-5 °C
Siedepunkt: 75 °C/0.25 · 75 °C/0.25 mmHg (lit.)
Dichte: 1.027 g/mL · 1.027 g/mL at 25 °C (lit.)
Dampfdruck: 1.04 hPa · 1.04 hPa (20 °C)
Brechungsindex: 20 · n20/D 1.420(lit.)
Flammpunkt: 223 °F · 223 °F
storage temp.: 30 °C · Store below +30°C.
Löslichkeit: Chloroform (Slightly), Ethyl Acetate (Slightly)
Aggregatzustand: Liquid
Farbe: Clear to slightly turbid yellow-orange to red
Wasserlöslichkeit: insoluble
BRN: 1912326 · 1912326
InChI: InChI=1S/C8H14N2O4/c1-5(2)13-7(11)9-10-8(12)14-6(3)4/h5-6H,1-4H3
InChIKey: VVWRJUBEIPHGQF-UHFFFAOYSA-N
SMILES: N(C(OC(C)C)=O)=NC(OC(C)C)=O
CAS Datenbank: 2446 · 2446-83-5(CAS DataBase Reference)

Sicherheit und Regulatorisches

Sicherheitsdaten

F: 4.10-8
wgk: 1
ridadr: UN 3082 9/PG 3
hs_code: 29270000
risk_code: 36/38-51/53-5-43-36/37/38-11-48/20/22-40
hazard_code: Xn,Xi,N,F
hazard_note: Harmful/Irritant
safety_code: 36-61-47A-36/37/39-29-26-16-60-36/37
hazard_class: 9
packing_group: III
Speicherklasse: 10 - Combustible liquids
Hazard Classifications: Aquatic Chronic 2Carc. 2Eye Irrit. 2Skin Irrit. 2STOT RE 2STOT SE 3

Chemie und Industrie

Anwendungen · 1 Eintrag

VerwendenDiisopropyl Azodicarboxylate is an azodicarboxylic acid derivative used as a reagent in the production of many organic compounds. Diisopropyl Azodicarboxylate is commonly used as an oxidizer in Mitsun obu reactions and can also serve as a selective deprotectant of N-benzyl groups in the presence of other protecting groups.