Dimethyl-2,2'-azobis(2-methylpropionat)

1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)

HCID 75763CAS 2589-57-3

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Grundinformationen

Standard-SMILES: COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC
InChIKey: ZQMHJBXHRFJKOT-UHFFFAOYSA-N
Summenformel: C10H18N2O4
Durchschnittliche Molmasse: 230,26 g/mol
Monoisotopische Masse: 230,12665706

Namen und Bezeichner

Bevorzugter Name: 1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)
IUPAC: methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate
Lokaler Name: Dimethyl-2,2'-azobis(2-methylpropionat)
Englischer Name: Dimethyl 2,2'-azobis(2-methylpropionate)
Summenformel: C10H18N2O4
Molmasse: 230.26

Namen und Synonyme

2589-57-31,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis[2-methylpropanoate]RefChem:196631Dimethyl 2,2'-azobis(2-methylpropionate)Dimethyl 2,2'-(diazene-1,2-diyl)bis(2-methylpropanoate)methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoatedimethyl 2,2'-azobisisobutyrateG88X6P053Wdimethyl 2,2-azobis(2-methylpropionate)Dimethyl-2,2'-azobis(2-methylpropionate)2,2-Azobisisobutyric acid dimethyl ester

Weitere Namen anzeigen

AIBMEV-601MAIBDYPR0396AIBME V601C10H18N2O4dimethyl 2,2'2-methylpropionateDimethyl 2,2'-Azobis-azobis(2-methylpropionate)

MFCD00085253Propanoic acid, 2,2'-(1,2-diazenediyl)bis(2-methyl-, 1,1'-dimethyl esterEINECS 219-976-6UNII-G88X6P053WAIBME cpddimethyl azodiisobutyratedimethyl 2,2'-azobis(2-methylpropanoate)dimethyl azobisisobutyrate

Datenbank-Bezeichner

CAS: 2589-57-3
PubChem CID: 75763
DTXSID: DTXSID701031497
UNII: G88X6P053W
EC Number: 219-976-6
Nikkaji: J117.182H

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 1,6
Polarare Oberfläche (TPSA): 77,3 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 6
Frei drehbare Bindungen: 6
Schwere Atome: 16
Formalladung: 0
Komplexität: 278

Experimentelle und physikochemische Eigenschaften

Physical DescriptionDry Powder

Physikochemische Eigenschaften

Schmelzpunkt: 22 · 22-28°C
Siedepunkt: 248.3 · 248.3±25.0 °C(Predicted)
Dichte: 1.06 · 1.06±0.1 g/cm3(Predicted)
Dampfdruck: 2.85 Pa · 2.85Pa at 20℃
storage temp.: 2 · Storage temp. 2-8°C
Wasserlöslichkeit: insoluble
InChI: InChI=1S/C10H18N2O4/c1-9(2,7(13)15-5)11-12-10(3,4)8(14)16-6/h1-6H3
InChIKey: ZQMHJBXHRFJKOT-UHFFFAOYSA-N
SMILES: N(C(C)(C)C(OC)=O)=NC(C)(C)C(OC)=O
LogP: 2.47 at · 2.47 at 25℃
CAS Datenbank: 2589 · 2589-57-3(CAS DataBase Reference)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H242 (100%): Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]

P210, P234, P235, P240, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P304+P340, P305+P351+P338, P317, P330, P337+P317, P370+P378, P391, P403, P410, P411, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 112 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 3 Einträge

Propanoic acid, 2,2'-(1,2-diazenediyl)bis[2-methyl-, 1,1'-dimethyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Propanoic acid, 2,2'-(1,2-diazenediyl)bis[2-methyl-, 1,1'-dimethyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 30-08-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/28213

Hazard Classes and CategoriesSelf-react. D (100%)

Sicherheitsdaten

tsca: TSCA listed
hs_code: 29270000

Chemie und Industrie

Verwendung und Herstellung

U.S. Production2023: 4,850 lb

Industry UsesPolymerization promoter

General Manufacturing Information · 2 Einträge

Plastics Material and Resin Manufacturing

Propanoic acid, 2,2'-(1,2-diazenediyl)bis[2-methyl-, 1,1'-dimethyl ester: ACTIVE

Anwendungen · 1 Eintrag

VerwendenDimethyl 2,2'-azobis(2-methylpropionate) is a nitrile-free, oil-soluble azo polymerization initiator with polymerization activity similar to AIBN. However, it has fewer toxic by-products than AIBN, is safer and can be used as an alternative to AIBN. In addition, the highly volatile decomposition products can be removed during the polymer production process, and the polymer after polymerization is highly transparent, so it is expected to be used in semiconductors and liquid crystal displays(LCDs).