Bis(2-ethylhexyl)amine (HCID 7791)

Überblick

2,2'-diethylhexylamine is a clear colorless liquid with a slight ammonia-like odor. (NTP, 1992)

Namen und Bezeichner

Bevorzugter Name: Bis(2-ethylhexyl)amine
IUPAC: 2-ethyl-N-(2-ethylhexyl)hexan-1-amine
Lokaler Name: Bis(2-ethylhexyl)-amin
Englischer Name: Bis(2-ethylhexyl)amine
Summenformel: C16H35N
Molmasse: 241.46

Namen und Synonyme

Bis(2-ethylhexyl)amine106-20-71-Hexanamine, 2-ethyl-N-(2-ethylhexyl)-RefChem:1079934Di(2-ethylhexyl)amineBis-2-ethylhexylamine2-ethyl-N-(2-ethylhexyl)hexan-1-amine2,2'-DiethyldihexylamineDiethylhexylamineDihexylamine, 2,2'-diethyl-2,2'-DIETHYLHEXYLAMINENSC 5329

Weitere Namen anzeigen

DIISOOCTYLAMINED2HDI2 EHAis2-ethylhexyl4-DifluorobenzoateTwo isooctyl amineTwo-ethylhexyl aMineBis(2-ethylhexyl)amiBis-2-ethylhexylamin

2-Ethyl-N-(2-ethylhexyl)-1-hexanamineDTXSID7025053MFCD0000948927214-52-49U5Q5UV6DBNSC-5329Di-(2-ethylhexyl)amine1-Hexylamine, 2-ethyl-N-(2-ethylhexyl)-

Datenbank-Bezeichner

CAS: 106-20-7、27214-52-4
PubChem CID: 7791
DTXSID: DTXSID7025053
ChEMBL: CHEMBL1330355
ChEBI: CHEBI:193588
UNII: 9U5Q5UV6DB
EC Number: 203-372-4、248-331-1
Nikkaji: J27.961G

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 6,1
Polarare Oberfläche (TPSA): 12 Å²
H-Brücken-Donoren: 1
H-Brücken-Akzeptoren: 1
Frei drehbare Bindungen: 12
Schwere Atome: 17
Formalladung: 0
Komplexität: 128

Experimentelle und physikochemische Eigenschaften

Chemical ClassesNitrogen Compounds -> Amines, Aliphatic

Cosmetics · 2 Einträge

Personal care product

Antistatic; Hair conditioning

SpringerMaterials PropertiesOptical coefficient

Density0.8062 at 68 °F (NTP, 1992) - Less dense than water; will float

Solubilityless than 1 mg/mL at 70 °F (NTP, 1992)

Flash Point · 2 Einträge

270 °F (NTP, 1992)

270 °F

Physikochemische Eigenschaften

Schmelzpunkt: -60 °C · -60 °C
Siedepunkt: 123 °C5 · 123 °C5 mm Hg(lit.)
Dichte: 0.805 g/mL · 0.805 g/mL at 25 °C(lit.)
Dampfdruck: 0.0023 hPa · 0.0023 hPa (20 °C)
Brechungsindex: 20 · n20/D 1.443(lit.)
Flammpunkt: 230 °F · >230 °F
storage temp.: 30 °C · Store below +30°C.
Löslichkeit: 0.014 g/l · 0.014g/l
pka: 40 · 40(at 25℃)
Aggregatzustand: Liquid
Farbe: Clear colorless to slightly yellow
Wichte: 0.804 · 0.804 (20/4℃)
PH: 7 · >7 (H2O, 20℃)
Explosionsgrenze: 0.6 · 0.6-3.7%(V)
Wasserlöslichkeit: 0.2 g/L · <0.2 g/L (20 ºC)
BRN: 1748342 · 1748342
Stabilität: Stable. Combustible. Incompatible with oxidizing agents.
Kosmetik-Inhaltsstoffe Funktionen: ANTISTATIC
InChI: 1S/C16H35N/c1-5-9-11-15(7-3)13-17-14-16(8-4)12-10-6-2/h15-17H,5-14H2,1-4H3
InChIKey: SAIKULLUBZKPDA-UHFFFAOYSA-N
SMILES: CCCCC(CC)CNCC(CC)CCCC
LogP: 7.3 at · 7.3 at 25℃
CAS Datenbank: 106 · 106-20-7(CAS DataBase Reference)
NIST chemische Informationen: 1 · 1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)-(106-20-7)
EPA chemische Informationen: Di(2-ethylhexyl)amine (106-20-7)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

This chemical does not meet GHS hazard criteria for 0.1% (1 of 669) of reports.

Danger

H302+H312 (65.9%): Harmful if swallowed or in contact with skin [Warning Acute toxicity, oral; acute toxicity, dermal]

P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P320, P321, P330, P361+P364, P362+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 669 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Not Classified

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: 1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)-

1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 13-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/5450

Bis(2-ethylhexyl) amine: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelCorrosive

Fire HazardsThis chemical is combustible. (NTP, 1992)

Health HazardsSYMPTOMS: Symptoms of exposure to this compound may include irritation to the skin and eyes.

Hazards SummaryA skin and eye irritant; A lachrymator; [CAMEO] Toxic by inhalation; Harmful if skin contact or ingested; Causes burns; May cause pneumonitis and pulmonary edema after inhalation of high concentrations; [MSDSonline]

Reactive GroupAmines, Phosphines, and Pyridines

Sicherheit und Schutzausrüstung

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide, or Halon extinguisher. (NTP, 1992)

First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 Eintrag

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:

Personal Protective Equipment (PPE) · 1 Eintrag

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.

Toxicity DataLC50 (rat) = 920 mg/m3/4H; [MSDSonline]

Sicherheitsdaten

wgk: 2
tsca: TSCA listed
ridadr: UN 2735 8/PG 2
hs_code: 29211980
RTECS-Nr.: IH6825000
risk_code: 21/22-34
Toxizität: LD50 orally in Rabbit: 1008 mg/kg LD50 dermal Rabbit 956 mg/kg
hazard_code: C,Xi
hazard_note: Irritant/Corrosive
safety_code: 26-36/37/39-45-36
hazard_class: 8
packing_group: III
Speicherklasse: 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
Hazard Classifications: Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 4 OralAquatic Chronic 1Eye Dam. 1Skin Corr. 1B
Selbstentzündungstemperatur: 230 °C

Chemie und Industrie

Verwendung und Herstellung

U.S. Production2023: 100,000 - <250,000 lb

Industry UsesCorrosion inhibitor

Use ClassificationCosmetics -> Antistatic; Hair conditioning

General Manufacturing Information · 2 Einträge

Petroleum Lubricating Oil and Grease Manufacturing

1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)-: ACTIVE

Anwendungen

VerwendenBis(2-ethylhexyl)amine (BEA) was used in the synthesis of stable nanosized CdS particles coated by an oriented monolayer of chemically bonded BEA molecules