1,5-Dibrompentan

1,5-Dibromopentane

HCID 8100CAS 111-24-0
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Grundinformationen

Standard-SMILES
BrCCCCCBr
InChIKey
IBODDUNKEPPBKW-UHFFFAOYSA-N
Summenformel
C5H10Br2
Durchschnittliche Molmasse
229,94 g/mol
Monoisotopische Masse
227,91492452

Namen und Bezeichner

Bevorzugter Name
1,5-Dibromopentane
IUPAC
1,5-dibromopentane
Lokaler Name
1,5-Dibrompentan
Englischer Name
1,5-Dibromopentane
Summenformel
C5H10Br2
Molmasse
229.94

Namen und Synonyme

1,5-DIBROMOPENTANE111-24-0Pentamethylene dibromidePentamethylene bromidePentane, 1,5-dibromo-DTXSID2049395NSC-5373B8Q228QYS1DTXCID9029354RefChem:73462203-849-71,5-dibromo-pentane
Weitere Namen anzeigen
PENTANE-1,5-DIBROMIDEBr(CH2)5Br1,5-Dibrompentan1,5-dibromo-pentanPentan-1,5-dibromidPentane,1,5-dibromo-
MFCD00000268NSC 53731,5-dibrompentanePentane,5-dibromo-Dibromo-1,5 pentaneDIBROMOPENTANE, 1,5-NSC5373CS-W019956

Datenbank-Bezeichner

CAS
111-24-0
PubChem CID
8100
DTXSID
DTXSID2049395
ChEMBL
CHEMBL3182198
UNII
B8Q228QYS1
EC Number
203-849-7
Nikkaji
J5.106C

Eigenschaften

Berechnete Struktureigenschaften

XLogP
2,8
Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
4
Schwere Atome
7

Experimentelle und physikochemische Eigenschaften

Chemical ClassesOther Classes -> Halogenated Aliphatics, Saturated
SpringerMaterials PropertiesBoiling point
Physical Description · 2 Einträge

CBI

Light brown liquid; [Sigma-Aldrich MSDS]

Physikochemische Eigenschaften

Schmelzpunkt
-34 °C · -34 °C (lit.)
Siedepunkt
110 °C/15 · 110 °C/15 mmHg (lit.)
Dichte
1.688 g/mL · 1.688 g/mL at 25 °C (lit.)
Dampfdichte
8 · 8 (vs air)
Brechungsindex
20 · n20/D 1.512(lit.)
Flammpunkt
230 °F · >230 °F

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Warning

H302 (12.7%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 55 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: Pentane, 1,5-dibromo-

Pentane, 1,5-dibromo- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Pentane, 1,5-dibromo- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 31-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/25661

1,5-Dibromopentane: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryA skin and strong eye irritant; [Sigma-Aldrich MSDS] See 2-Bromopentane.
Hazard Classes and CategoriesAcute Tox. 4 (12.7%)

Sicherheitsdaten

wgk
3
tsca
TSCA listed
hs_code
29033036
RTECS-Nr.
SA0320000
risk_code
36/38-22
hazard_code
Xi,Xn

Chemie und Industrie

Verwendung und Herstellung

U.S. Production2023: <50,000 lb
Industry UsesCatalyst
General Manufacturing Information · 2 Einträge

All Other Basic Organic Chemical Manufacturing

Pentane, 1,5-dibromo-: ACTIVE

Anwendungen · 1 Eintrag

Verwenden1,5-Dibromopentane is used in the preparation of 1,5-di-Grignard reagent and novel spirocyclic pyrrolidones. It acts as a growth supplement for Yarrowia lipolytica 3589, a tropical marine yeast. It is involved in the synthesis of N-alkylated piperidine as well as tetrydrothiopyran (thiane) by reaction with primary amine and sodium sulfide respectively.

Darstellung · 1 Eintrag

synthetische1,5-Dibromopentane was obtained by ring-opening bromination of tetrahydropyran. In a 500ml flask, add 250g of 48% hydrobromic acid, 75g of concentrated sulfuric acid, 21.5g of redistilled tetrahydropyran (86.5-87.5°C fraction) in turn to a reflux condenser and heat the brown mixture gently to reflux for 3h. After cooling to room temperature, partition the lower layer of dibromide and wash each with saturated sodium carbonate solution and water once. Dried with anhydrous calcium chloride. Distill under reduced pressure and collect the 104-106°C (2.53 kPa) fraction as 1,5-dibromopentane in 46-47 g yield and 80-82% yield.1,5-Dibromopentane synthesis route

Vor- und nachgelagerte Produkte

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国药集团化学试剂有限公司86-21-63210123 · [email protected]
北京华美互利生物化工010-56205725 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

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