N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamin

N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine

HCID 82125

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Grundinformationen

CAS: 7688-51-9
Standard-SMILES: C=CCN([Si](C)(C)C)[Si](C)(C)C
InChIKey: CVNCFZIIZGNVFD-UHFFFAOYSA-N
Summenformel: C9H23NSi2
Durchschnittliche Molmasse: 201,46 g/mol
Monoisotopische Masse: 201,13690281

Namen und Bezeichner

Bevorzugter Name: N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine
IUPAC: N,N-bis(trimethylsilyl)prop-2-en-1-amine
Lokaler Name: N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamin
Englischer Name: N-Allyl-n N-bis(trimethylsilyl)amine
Summenformel: C9H23NSi2
Molmasse: 201.46

Namen und Synonyme

7688-51-9N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamineEINECS 231-699-2DTXSID50227684Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-RefChem:828934DTXCID00150175231-699-2N,N-Bis(trimethylsilyl)allylamineN-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINEN,N-bis(trimethylsilyl)prop-2-en-1-amineN-Allyl-N,N-bis(trimethylsilyl)amine

Weitere Namen anzeigen

Ditrimethylsilyl allylamineN,N'-bis(trimethylsilyl)allylamineProp-2-en-1-ylbis(trimethylsilyl)amineN-Allyl-N,N-bis(trimethylsilyl)amine 97%2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN&

3-Bis(trimethylsilyl)amino-1-propene(prop-2-en-1-yl)bis(trimethylsilyl)amineMFCD00545193N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silanamineC9H23NSi2Allylbis(trimethylsilyl)amine578932_ALDRICH, EINECS 231-699-2, MolPort-003-937-319, N,N-Bis(trimethylsilyl)allylamine, CID82125, N-Allyl-N,N-bis(trimethylsilyl)amine, N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine, Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-, 7688-51-9AHL726ZXM9

Datenbank-Bezeichner

CAS: 7688-51-9
PubChem CID: 82125
DTXSID: DTXSID50227684
UNII: AHL726ZXM9
EC Number: 231-699-2
Nikkaji: J125.864H

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 3,2 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 1
Frei drehbare Bindungen: 4
Schwere Atome: 12
Formalladung: 0
Komplexität: 139

Physikochemische Eigenschaften

Siedepunkt: 72 °C/15 · 72 °C/15 mmHg (lit.)
Dichte: 0.816 g/mL · 0.816 g/mL at 25 °C (lit.)
Brechungsindex: 20 · n20/D 1.440(lit.)
Flammpunkt: 109 °F · 109 °F
Aggregatzustand: liquid
Wichte: 0.817 · 0.817
InChI: 1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3
InChIKey: CVNCFZIIZGNVFD-UHFFFAOYSA-N
SMILES: C[Si](C)(C)N(CC=C)[Si](C)(C)C

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]；H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chemical: Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Hazard Classes and CategoriesFlam. Liq. 3 (100%)；Skin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (100%)

Regulatorische Informationen

Regulatory Information · 2 Einträge

Chemical: Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Sicherheitsdaten

wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 3
risk_code: 10-36/37/38
hazard_code: Xi
safety_code: 16-26-36/37
Speicherklasse: 3 - Flammable liquids
Hazard Classifications: Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationSilanamine, 1,1,1-trimethyl-N-2-propen-1-yl-N-(trimethylsilyl)-: ACTIVE

Anwendungen · 1 Eintrag

VerwendenN-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare: Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions. Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride. Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.