HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HCID 82125Erstellt: 27. Oktober 2026
N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamin
Einecs 231-699-2 · Ditrimethylsilyl allylamine · Allylbis(trimethylsilyl)amine · N,N'-bis(trimethylsilyl)allylamine · 3-bis(trimethylsilyl)amino-1-propene · N-Allyl-n N-bis(trimethylsilyl)amine · Prop-2-en-1-ylbis(trimethylsilyl)amine · N,N-bis(trimethylsilyl)prop-2-en-1-amine
https://huagongshe.com/de/chemical/82125
Identifikatoren & physikalische Daten
| CAS No. | 7688-51-9 |
|---|
| Summenformel | C9H23NSi2 |
|---|
| Durchschnittliche Molmasse | 201,46 g/mol |
|---|
| Monoisotopische Masse | 201,13690281 g/mol |
|---|
| SMILES | C=CCN([Si](C)(C)C)[Si](C)(C)C |
|---|
| InChIKey | CVNCFZIIZGNVFD-UHFFFAOYSA-N |
|---|
| PubChem CID | 82125 |
|---|
| EC No. | 231-699-2 |
|---|
| DTXSID | DTXSID50227684 |
|---|
| Lokaler Name | N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamin |
|---|
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 3,2 |
|---|
| H-Brücken-Donoren | 0 |
|---|
| H-Brücken-Akzeptoren | 1 |
|---|
| Frei drehbare Bindungen | 4 |
|---|
| Schwere Atome | 12 |
|---|
| Formalladung | 0 |
|---|
| Komplexität | 139 |
|---|
| Siedepunkt | 72 °C/15 mmHg (lit.) |
|---|
| Dichte | 0.816 g/mL at 25 °C (lit.) |
|---|
| Brechungsindex | n20/D 1.440(lit.) |
|---|
| Flammpunkt | 109 °F |
|---|
| Aggregatzustand | liquid |
|---|
| Wichte | 0.817 |
|---|
| InChI | 1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3 |
|---|
| InChIKey | CVNCFZIIZGNVFD-UHFFFAOYSA-N |
|---|
| SMILES | C[Si](C)(C)N(CC=C)[Si](C)(C)C |
|---|
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH226 (100%): Flammable liquid and vapor [Warning Flammable liquids]H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposureRespiratory tract irritation]P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|
| Regulatorische Informationen | Chemical: Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance. |
|---|
| Hazard Classes and Categories | Flam. Liq. 3 (100%)Skin Irrit. 2 (100%)Eye Irrit. 2 (100%)STOT SE 3 (100%) |
|---|
| Wassergefährdungsklasse (WGK) | 3 |
|---|
| TSCA-Inventar-Status | TSCA listed |
|---|
| UN-Transportnummer | UN 1993 3/PG 3 |
|---|
| R-Sätze (R) | 10-36/37/38 |
|---|
| Gefahrensymbole | Xi |
|---|
| Sicherheitshinweise (S) | 16-26-36/37 |
|---|
| Lagerklasse | 3 - Flammable liquids |
|---|
| Gefahrenklasse | |
|---|
Anwendungen & Verwendung
Verwenden
N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare: Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions. Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride. Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.
