1-Bromdodecan

1-Bromododecane

HCID 8919CAS 143-15-7

Grundinformationen

Standard-SMILES
CCCCCCCCCCCCBr
InChIKey
PBLNBZIONSLZBU-UHFFFAOYSA-N
Summenformel
C12H25Br
Durchschnittliche Molmasse
249,23 g/mol
Monoisotopische Masse
248,1139629

Namen und Bezeichner

Bevorzugter Name
1-Bromododecane
IUPAC
1-bromododecane
Lokaler Name
1-Bromdodecan
Englischer Name
1-Bromododecane
Summenformel
C12H25Br
Molmasse
249.23

Namen und Synonyme

1-Bromododecane143-15-7Lauryl bromideDodecyl bromideDodecane, 1-bromo-DTXSID2044395DTXCID002439590T93TX09DNSC-6786RefChem:75159205-587-9n-Dodecyl bromide
Weitere Namen anzeigen
1-DodecylbromideBROMODODECANLaurlybromideJACS-143-15-7Lauroylbromide1-Dodecylbromid1-bromo-dodecan
Dodecane, bromo-bromododecane1-bromo dodecane1-bromo-dodecaneC12H25Br1-BROMO-N-DODECANEMFCD00000225NSC 6786

Datenbank-Bezeichner

CAS
143-15-7
PubChem CID
8919
DTXSID
DTXSID2044395
ChEMBL
CHEMBL3184907
UNII
90T93TX09D
EC Number
205-587-9
Nikkaji
J2.029J

Eigenschaften

Berechnete Struktureigenschaften

XLogP
7,1
Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
10
Schwere Atome
13

Experimentelle und physikochemische Eigenschaften

Chemical ClassesOther Classes -> Halogenated Aliphatics, Saturated
SpringerMaterials PropertiesBoiling point
Density1.038 @25 °C
Physical Description · 2 Einträge

Liquid

Liquid; [Merck Index] Colorless liquid with a weak odor; [Alfa Aesar MSDS]

Physikochemische Eigenschaften

Schmelzpunkt
11 · −11-−9 °C(lit.)
Siedepunkt
134 · 134-135 °C6 mm Hg(lit.)
Dichte
1.04 g/mL · 1.040 g/mL at 20 °C
Dampfdichte
8.6 · 8.6 (vs air)
Brechungsindex
20 · n20/D 1.458(lit.)
Flammpunkt
230 °F · >230 °F

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

This chemical does not meet GHS hazard criteria for 22.9% (58 of 253) of reports.

Danger

H304 (41.1%): May be fatal if swallowed and enters airways [Danger Aspiration hazard]

P261, P264, P264+P265, P271, P280, P301+P316, P302+P352, P304+P340, P305+P351+P338, P319, P321, P331, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 253 reports by companies from 13 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: Dodecane, 1-bromo-

Dodecane, 1-bromo- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Dodecane, 1-bromo- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 29-04-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/10302

Dodecane, 1-bromo-: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryMay cause irritation; [Alfa Aesar MSDS] See 1-Bromopropane and 2-Bromopentane.
Hazard Classes and CategoriesAsp. Tox. 1 (41.1%)

Sicherheit und Schutzausrüstung

Protective Action Criteria (PAC) · 3 Einträge

12 [mg/m3]

130 [mg/m3]

790 [mg/m3]

Toxikologische Informationen

Adverse EffectsNeurotoxin - Acute solvent syndrome

Sicherheitsdaten

F
19
wgk
3
tsca
TSCA listed
hs_code
29033036
risk_code
36/37/38
hazard_code
Xi

Chemie und Industrie

Verwendung und Herstellung

U.S. Production2023: 250,000 - <550,000 lb
Consumer UsesAbrasives
Industry UsesAbrasives
General Manufacturing Information · 2 Einträge

Mining (except Oil and Gas) and support activities

Dodecane, 1-bromo-: ACTIVE

Anwendungen · 2 Einträge

Verwenden1-Bromododecane is used as a solvent. It is used as an intermediate to manufacture surfactant, pharmaceuticals and other organic compounds.

Verwenden1-Bromododecane have assumed considerable importance as starting materials for the production of many types of organic derivatives. The major use for 1-Bromododecane with 12 – 16 carbon atomsisinthe production of alkyldimethylamines by the nucleophilic displacement of bromide ion with dimethylamine. These amines are used as intermediates in the manufacture of fatty amine oxides and alkyl dimethyl benzyl quaternary ammonium salts, which are used in a wide range of products because of their biological (germicidal) or physical (cationic) properties. Minor amounts of 1-Bromododecane are used to produce insect pheromones, phasetransfer catalysts, and other useful specialty chemicals.

Darstellung · 1 Eintrag

synthetische1-Bromododecane is synthesized by the action of 1-dodecanol and hydrobromic acid. The 1-dodecanol is added to the enameled glass reaction pot, stirred and cooled, and sulfuric acid is slowly added. Stir for 1h, then add hydrobromic acid. The temperature is gradually increased to 90-95℃, and the reaction is stirred for 8h. After the reaction, the temperature is lowered to 30℃ and left for 8h. The acid layer is separated, and the oil layer is adjusted to pH 8 with dilute alkali solution, and the alkali solution is separated and washed with 50% ethanol. Distill under reduced pressure and collect 140-200℃ (3.33kPa) fractions to obtain refined 1-bromododecane.

Anbieter50 Anbieter

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
爱斯特(成都)生物制药股份有限公司+86-28-85122536 85324413 · [email protected]
科瑞迪化学400-821-5857 021-64326257 · [email protected]

Zugehörige Reaktionen

192

Verknüpfte Notizen

Wird geladen…