Grundinformationen
- Standard-SMILES
N[C@H](Cc1c[nH]c2ccccc12)C(=O)O- InChIKey
QIVBCDIJIAJPQS-SECBINFHSA-N- Summenformel
- C11H12N2O2
- Durchschnittliche Molmasse
- 204,22 g/mol
- Monoisotopische Masse
- 204,08987762
Überblick
D(+)-tryptophan is a white solid. (NTP, 1992)
Namen und Bezeichner
- Bevorzugter Name
- D-Tryptophan
- IUPAC
- (2R)-2-amino-3-(1H-indol-3-yl)propanoic acid
- Lokaler Name
- D-(+)-Tryptophan
- Englischer Name
- D-Tryptophan
- Summenformel
- C11H12N2O2
- Molmasse
- 204.23
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
153-94-6- PubChem CID
- 9060
- DTXSID
DTXSID0046989- ChEMBL
CHEMBL292303- ChEBI
CHEBI:16296- UNII
- 7NS97N9H1G
- EC Number
- 205-819-9
- Nikkaji
- J9.185E
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- -1,1
- Polarare Oberfläche (TPSA)
- 79,1 Ų
- H-Brücken-Donoren
- 3
- H-Brücken-Akzeptoren
- 3
- Frei drehbare Bindungen
- 3
- Schwere Atome
- 15
- Formalladung
- 0
- Komplexität
- 245
Experimentelle und physikochemische Eigenschaften
Melting Point
527 to 540 °F (NTP, 1992)
282-85 dec °C
282 - 85 °C
Physical Description
D(+)-tryptophan is a white solid. (NTP, 1992)
White solid; [CAMEO] White powder; [Alfa Aesar MSDS]
Solid
Collision Cross Section
151.5 Ų [M-H]- [CCS Type: DT; Buffer gas: N2; Ionization: ESI-; Dataset: TOXCAST; Source Identifier: DTXSID0046989]
142.6 Ų [M-H]-
Physikochemische Eigenschaften
- Schmelzpunkt
- 282 · 282-285 °C (dec.)(lit.)
- Siedepunkt
- 342.72 °C · 342.72°C (rough estimate)
- Dichte
- 1.1754 · 1.1754 (rough estimate)
- Brechungsindex
- 31 ° · 31 ° (C=1, H2O)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- Löslichkeit
- Aqueous Base (Slightly), DMSO (Slightly, Heated, Sonicated), Methanol (Slightly)
- pka
- 2.3 · 2.30±0.10(Predicted)
- Aggregatzustand
- Powder
- Farbe
- White to slightly yellow
- Biologische Quelle
- synthetic (organic)
- Wasserlöslichkeit
- 11 g/L · 11 g/L (20 ºC)
- BRN
- 86198 · 86198
- Stabilität
- Stable. Incompatible with oxidizing agents.
- InChI
- 1S/C11H12N2O2/c12-9(11(14)15)5-7-6-13-10-4-2-1-3-8(7)10/h1-4,6,9,13H,5,12H2,(H,14,15)/t9-/m1/s1
- InChIKey
- QIVBCDIJIAJPQS-SECBINFHSA-N
- SMILES
- N[C@H](Cc1c[nH]c2ccccc12)C(O)=O
- LogP
- 0.704 · 0.704 (est)
- CAS Datenbank
- 153 · 153-94-6(CAS DataBase Reference)
- EPA chemische Informationen
- D-Tryptophan (153-94-6)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
This chemical does not meet GHS hazard criteria for 87.5% (7 of 8) of all reports.
Warning
H315 (12.5%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 8 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Reactivity Profile
Acidic salts, such as D(+)-TRYPTOPHAN, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
Sicherheit und Schutzausrüstung
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Nonfire Spill Response
SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, you should dampen the solid spill material with alcohol, then transfer the dampened material to a suitable container. Use absorbent paper dampened with alcohol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminate area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Personal Protective Equipment (PPE)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
Sicherheitsdaten
- F
- 8
- wgk
- 3
- tsca
- TSCA listed
- hs_code
- 29339990
- RTECS-Nr.
- YN6129000
- risk_code
- 36/37/38-41-37/38-22
- hazard_code
- Xi
- safety_code
- 24/25-36/37/39-36-26
- hazard_class
- IRRITANT
- Speicherklasse
- 11 - Combustible Solids
Chemie und Industrie
Verwendung und Herstellung
Anwendungen
VerwendenAn essential amino acid found in naturally produced pedtides. Unlike its stereoisomer, L-tryptophan, it is not used in structural or enzyme proteins.
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Ergänzende Hinweise
DefinitionChEBI: The D-enantiomer of tryptophan.
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