Allyltributylstannan

Allyltributylstannane

HCID 90628CAS 24850-33-7

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Grundinformationen

Standard-SMILES: C=C[CH2][Sn]([CH2]CCC)([CH2]CCC)[CH2]CCC
InChIKey: YLGRTLMDMVAFNI-UHFFFAOYSA-N
Summenformel: C15H32Sn
Durchschnittliche Molmasse: 331,12 g/mol
Monoisotopische Masse: 332,15259572

Namen und Bezeichner

Bevorzugter Name: Allyltributylstannane
IUPAC: tributyl(prop-2-enyl)stannane
Lokaler Name: Allyltributylstannan
Englischer Name: Allyltributyltin
Summenformel: C15H32Sn
Molmasse: 331.12

Namen und Synonyme

AllyltributyltinAllyltributylstannane24850-33-7UNII-AOR8OD4103AOR8OD4103Tributyl-2-propen-1-ylstannaneEINECS 246-494-3ALLYLTRIBUTYLSTANNANE [MI]DTXSID50179553RefChem:110920DTXCID10102044246-494-3

Weitere Namen anzeigen

Tributylallylstannaneallyltri-n-butylstannane2-PropenyltributylstannaneTRIBUTYL-2-PROPENYLSTANNANESKL1093Allytri-N-Butyltin

YLGRTLMDMVAFNI-UHFFFAOYSA-NAllyltri-n-ButyltinStannane, tributyl-2-propenyl-Allyl(tributyl)stannanetributyl(prop-2-en-1-yl)stannanetributyl(prop-2-enyl)stannaneStannane, tributyl-2-propen-1-yl-allyl tributylstannane

Datenbank-Bezeichner

CAS: 24850-33-7
PubChem CID: 90628
DTXSID: DTXSID50179553
UNII: AOR8OD4103
EC Number: 246-494-3
Nikkaji: J236.685A

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 0 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 0
Frei drehbare Bindungen: 11
Schwere Atome: 16
Formalladung: 0
Komplexität: 141

Experimentelle und physikochemische Eigenschaften

Endocrine DisruptorsPotential endocrine disrupting compound

Physikochemische Eigenschaften

Schmelzpunkt: 134 · 134-135 °C
Siedepunkt: 88 · 88-92 °C0.2 mm Hg(lit.)
Dichte: 1.068 g/mL · 1.068 g/mL at 25 °C(lit.)
Brechungsindex: 20 · n20/D 1.486(lit.)
Flammpunkt: 230 °F · >230 °F
storage temp.: 2 · 2-8°C
Löslichkeit: Chloroform (Slightly), Methanol (Slightly)
Aggregatzustand: Liquid
Farbe: Clear colorless
Wichte: 1.068 · 1.068
Wasserlöslichkeit: Immiscible with water.
BRN: 3588340 · 3588340
Stabilität: Air Sensitive
InChI: 1S/3C4H9.C3H5.Sn/c3*1-3-4-2;1-3-2;/h3*1,3-4H2,2H3;3H,1-2H2;
InChIKey: YLGRTLMDMVAFNI-UHFFFAOYSA-N
SMILES: CCCC[Sn](CCCC)(CCCC)CC=C
CAS Datenbank: 24850 · 24850-33-7(CAS DataBase Reference)
NIST chemische Informationen: Allyltributyltin(24850-33-7)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P260, P264, P264+P265, P270, P273, P280, P301+P316, P302+P352, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory InformationStannane, tributyl-2-propenyl-: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesAcute Tox. 3 (100%)

Sicherheitsdaten

F: 13
wgk: 3
tsca: No
ridadr: UN 2788 6.1/PG 2
hs_code: 29319019
risk_code: 21-25-36/38-48/23/25-50/53-23/24/25
hazard_code: T,N
safety_code: 35-36/37/39-45-60-61-28-27-26
hazard_class: 6.1
packing_group: II
Speicherklasse: 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
Hazard Classifications: Acute Tox. 3 OralAcute Tox. 4 DermalAquatic Acute 1Aquatic Chronic 1Eye Irrit. 2Repr. 1BSkin Irrit. 2STOT RE 1

Chemie und Industrie

Anwendungen · 1 Eintrag

VerwendenAllylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7