Trichloroacetonitrile → 3-{4-[2,4-bis(trichloromethyl)-s-triazine-6-yl]phenyl thio}propionic Acid

HRID 1008105

Reaktionsgleichung

[C:1]([C:3]1[CH:8]=[CH:7][C:6]([S:9][CH2:10][CH2:11][C:12]([OH:14])=[O:13])=[CH:5][CH:4]=1)#[N:2].[Cl:15][C:16]([Cl:20])([Cl:19])[C:17]#[N:18].[Al](Br)(Br)Br>>[Cl:15][C:16]([Cl:20])([Cl:19])[C:17]1[N:18]=[C:17]([C:16]([Cl:20])([Cl:19])[Cl:15])[N:18]=[C:1]([C:3]2[CH:4]=[CH:5][C:6]([S:9][CH2:10][CH2:11][C:12]([OH:14])=[O:13])=[CH:7][CH:8]=2)[N:2]=1

Komponenten

Edukt 3

HCID 11011Trichloroacetonitrile

HCID 24409Aluminum bromide

HCID 226666023-[(4-Cyanophenyl)sulfanyl]propanoic acid

Produkt 1

HCID 601112433-{4-[2,4-bis(trichloromethyl)-s-triazine-6-yl]phenyl thio}propionic Acid

Reaktionsbedingungen

Temperatur: 60 °C

Versuchsvorschrift

The reaction mixture of 22 g of 3-(4-cyanophenyl thio)propionic acid, 150 g of trichloroacetonitrile, and 2 g of AlBr3 was heated to 60° C. in order to dissolve the initially undissolved starting materials, and was bubbled by dry HCl at room temperature.

Aufarbeitung

dissolutionto dissolve the
customwas bubbled by dry HCl at room temperature

Quellen und Nachweise

ORD-Eintrag: ord-55159e626f014794ad064a59718bac78
Quelldatensatz: uspto-grants-2004_09
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US06797739B1

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