1,8-Dichloroanthraquinone → 1,8-Bis{[2-(dimethylamino)ethyl]amino}anthracene-9,10-dione

HRID 1019483

Reaktionsgleichung

Reaktionsgleichung von HRID 1019483
Cl[C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][C:12]=3Cl)[C:7](=[O:18])[C:6]=2[CH:5]=[CH:4][CH:3]=1.[CH3:19][N:20]([CH3:24])[CH2:21][CH2:22][NH2:23]>O>[CH3:19][N:20]([CH3:24])[CH2:21][CH2:22][NH:23][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][C:12]=3[NH:23][CH2:22][CH2:21][N:20]([CH3:24])[CH3:19])[C:7](=[O:18])[C:6]=2[CH:5]=[CH:4][CH:3]=1

Komponenten

4

Edukt 2

HCID 67081,8-DichloroanthraquinoneHCID 66053N,N-Dimethylethylenediamine

Produkt 1

HCID 143201191,8-Bis{[2-(dimethylamino)ethyl]amino}anthracene-9,10-dione

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

A mixture of 1,8-dichloroanthraquinone (5.5 g, 20 mmol) and N,N-dimethylethylenediamine (40 mL) was refluxed for 18 h. The mixture was cooled to room temperature and diluted with water to precipitate the title compound which was recrystallised from methanol to afford Compound 6 (4.5 g). The structure of Compound 6 is given below:

Aufarbeitung

  1. temperaturewas refluxed for 18 h
  2. customto precipitate the title compound which
  3. customwas recrystallised from methanol

Quellen und Nachweise

ORD-Eintrag
ord-98b4b17fa882481e9b2d696cfe3eed5d
Quelldatensatz
uspto-grants-2014_05
Patentnummer
US08715944B2

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