Oxalyl chloride → Acetyl chloride, (benzoyloxy)-

HRID 1032625Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1032625
[C:1]([O:9][CH2:10][C:11]([OH:13])=O)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(Cl)(=O)C([Cl:17])=O>C(Cl)(Cl)Cl>[C:1]([O:9][CH2:10][C:11]([Cl:17])=[O:13])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Komponenten

4

Edukt 2

HCID 65578Oxalyl chloride2×HCID 12647149HCID 12647149, Verbindung

Produkt 1

HCID 10888895Acetyl chloride, (benzoyloxy)-

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6212ChloroformLösungsmittel

Versuchsvorschrift

4.1 g (0.023 m) Benzoyloxy acetic acid (as synthesized in Example XIII) was combined with 2.96 ml (4.3 g, 0.032 m) oxalyl chloride in 50 ml petroleum ether. This was stirred under a CaSO4 drying tube for 5 hrs., at which time 2.0 ml more oxalyl chloride and 50 ml chloroform were added. The reaction was stirred overnight.

Aufarbeitung

  1. stirringThe reaction was stirred overnight

Quellen und Nachweise

ORD-Eintrag
ord-6eefa33d66e045669b238d42ac7779ea
Quelldatensatz
uspto-grants-1990_09
Patentnummer
US04959187

Notizen zur Reaktion

Wird geladen…