Tetralin → Biphenyl

HRID 1041820

Reaktionsgleichung

Reaktionsgleichung von HRID 1041820
C1C2C(=CC=CC=2)CCC1.[C:11]1([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=2S)[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>>[C:11]1([C:17]2[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=2)[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

Komponenten

3

Edukt 2

HCID 8404TetralinHCID 27604132-Phenylthiophenol

Produkt 1

HCID 7095Biphenyl

Reaktionsbedingungen

Temperatur
375 °C

Versuchsvorschrift

A volume of 1.5 ml of a tetralin solution containing 0.1 M of 2-phenylthiopheol was placed into 3 ml stainless-steel mini-bomb inside a dry-box. The mini-bomb was heated at 375° C. in an oven for a certain period of time and the content analyzed by GC/MS. Results in Table 1 below indicate desulfurization of 2-phenylthiophenol, giving biphenyl as the major product.

Aufarbeitung

  1. customResults in Table 1

Quellen und Nachweise

ORD-Eintrag
ord-af10a4291d544822bec950361b4f5258
Quelldatensatz
uspto-grants-2013_10
Patentnummer
US08557101B2

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