(2E)-3-(furan-3-yl)prop-2-enoic acid → 3-(Oxolan-3-yl)propanoic acid

HRID 1058746Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1058746
[O:1]1[CH:5]=[CH:4][C:3](/[CH:6]=[CH:7]/[C:8]([OH:10])=[O:9])=[CH:2]1.[H][H]>[Pd]>[O:1]1[CH2:5][CH2:4][CH:3]([CH2:6][CH2:7][C:8]([OH:10])=[O:9])[CH2:2]1

Komponenten

4

Edukt 2

HCID 643403(2E)-3-(furan-3-yl)prop-2-enoic acidHCID 178418361HCID 178418361, Verbindung

Produkt 1

HCID 2840903-(Oxolan-3-yl)propanoic acid

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 23938PalladiumKatalysator

Versuchsvorschrift

To a solution of trans-3-furanacrylic acid (10 g, 72.4 mmol) in industrial methylated spirits (50 mL) was added 10% palladium on carbon (1.0 g) at room temperature. The reaction vessel was charged with hydrogen gas to a pressure of 345 kPa and stirred at room temperature for 16 hours. The catalyst was removed by filtration and the filtrate was concentrated in vacuo to give the title compound as a colourless oil.

Aufarbeitung

  1. customThe catalyst was removed by filtration
  2. concentrationthe filtrate was concentrated in vacuo

Quellen und Nachweise

ORD-Eintrag
ord-6c863cb2aea242c3932cbfa3c441acd2
Quelldatensatz
uspto-grants-2003_02
Patentnummer
US06518282B1

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