Water → N-acetyl-2-benzylsulfinylacetamide

HRID 1065292Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1065292
[C:1]([NH:4][C:5](=[O:15])[CH2:6][S:7][CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)(=[O:3])[CH3:2].[OH2:16]>>[C:1]([NH:4][C:5](=[O:15])[CH2:6][S:7]([CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)=[O:16])(=[O:3])[CH3:2]

Komponenten

3

Edukt 2

HCID 962WaterHCID 12837900HCID 12837900, Verbindung

Produkt 1

HCID 20540297N-acetyl-2-benzylsulfinylacetamide

Versuchsvorschrift

To a solution of 0.011 mole of NaIO4 in 25 ml. of water which has been cooled to 5° C. is added 0.01 mole of N-acetyl-2-(benzylthio) acetamide. The reaction mixture is allowed to warm to room temperature and then stirred overnight and concentrated to dryness. Chromatography of the residue on 200 g. of silica gel eluting with ethyl acetate in hexane (25-75%) gives N-acetyl-2-benzylsulfinylacetamide.

Aufarbeitung

  1. concentrationconcentrated to dryness

Quellen und Nachweise

ORD-Eintrag
ord-bb12e9544b884a5a999e9e38ff883004
Quelldatensatz
uspto-grants-1982_05
Patentnummer
US04329363

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