Benzaldehyde → 2-(2-Phenylethenyl)-8-Quinolinol

HRID 1069523Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1069523
[OH:1][C:2]1[CH:3]=[CH:4][CH:5]=[C:6]2[C:11]=1[N:10]=[C:9]([CH3:12])[CH:8]=[CH:7]2.[CH:13](=O)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>>[C:14]1([CH:13]=[CH:12][C:9]2[CH:8]=[CH:7][C:6]3[C:11](=[C:2]([OH:1])[CH:3]=[CH:4][CH:5]=3)[N:10]=2)[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

Komponenten

3

Edukt 2

HCID 240BenzaldehydeHCID 132242-Methyl-8-hydroxyquinoline

Produkt 1

HCID 4698252-(2-Phenylethenyl)-8-Quinolinol

Versuchsvorschrift

A mixture of 8-hydroxyquinaldine (10.02 g) and benzaldehyde (16.8 mL) is heated at reflux overnight. The reaction is cooled to room temperature and vacuum distilled. After the excess benzaldehyde has distilled off, the residue remaining in the flask is dissolved in hot 95% EtOH. Any undissolved material is filtered off. The EtOH filtrate is cooled slowly to give the product as light yellow crystals (5.17 g).

Aufarbeitung

  1. temperatureis heated
  2. temperatureat reflux overnight
  3. distillationvacuum distilled
  4. distillationAfter the excess benzaldehyde has distilled off
  5. dissolutionis dissolved in hot 95% EtOH
  6. filtrationAny undissolved material is filtered off
  7. temperatureThe EtOH filtrate is cooled slowly

Quellen und Nachweise

ORD-Eintrag
ord-b0707d457aaf4320af484f7032e5d862
Quelldatensatz
uspto-grants-2001_06
Patentnummer
US06252080B1

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