Diethyl Ether → Butylnorbornene

HRID 1071224

Reaktionsgleichung

Reaktionsgleichung von HRID 1071224
F[C:2]1C([B-](C2C(F)=C(F)C(F)=C(F)C=2F)(C2C(F)=C(F)C(F)=C(F)C=2F)C2C(F)=C(F)C(F)=C(F)C=2F)=C(F)C(F)=C(F)C=1F.[Li+].CCOCC.[C:52]([C:56]1[CH:61]=[CH:60][CH:59]=[C:58]([C:62]([CH3:65])([CH3:64])C)N=1)([CH3:55])(C)C>C1(C)C=CC=CC=1.C([Pd]Cl)C=C>[CH2:61]([C:60]12[CH2:64][CH:62]([CH2:58][CH2:59]1)[CH:65]=[CH:2]2)[CH2:56][CH2:52][CH3:55]

Komponenten

6

Edukt 3

HCID 3283Diethyl EtherHCID 685102,6-Di-tert-butylpyridineHCID 23709652Lithium tetrakis(pentafluorophenyl)borate

Produkt 1

HCID 19091267Butylnorbornene

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 178455862HCID 178455862, VerbindungKatalysatorHCID 1140TolueneLösungsmittel4×

Versuchsvorschrift

A 50 weight percent solution of butylnorbornene (5.0 g, 0.033 mol) was prepared in toluene. Lithium tetrakis(pentafluorophenyl)borate.2.5 Et2O (0.0012 g, 0.0014 mmol) was combined with (allyl)palladiumchloride dimer (100 μl of a 1.4 mmol solution in toluene) and 2,6-di-t-butylpyridine (100 μl of a 2.9 mmol solution in toluene) in toluene and added to the monomer mixture. A polymeric puck formed within 5-10 min at room temperature.

Aufarbeitung

  1. additionadded to the monomer mixture
  2. customA polymeric puck formed within 5-10 min at room temperature

Quellen und Nachweise

ORD-Eintrag
ord-6f741e4bfe44433caac73c00e8934430
Quelldatensatz
uspto-grants-2005_06
Patentnummer
US06903171B2

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