Ethylamine → 29526-66-7

HRID 1071511Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1071511
[CH3:1][C:2]1[CH:10]=[CH:9][C:5]([C:6](Cl)=[O:7])=[CH:4][C:3]=1[N+:11]([O-])=O.[CH2:14]([NH2:16])[CH3:15]>C(Cl)Cl>[NH2:11][C:3]1[CH:4]=[C:5]([CH:9]=[CH:10][C:2]=1[CH3:1])[C:6]([NH:16][CH2:14][CH3:15])=[O:7]

Komponenten

4

Edukt 2

HCID 6341EthylamineHCID 663234-Methyl-3-nitrobenzoyl chloride

Produkt 1

HCID 1260797429526-66-7

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6344DichloromethaneLösungsmittel

Reaktionsbedingungen

Temperatur
0 °C

Versuchsvorschrift

4-methyl-3-nitro-benzoyl chloride (1.0 g, 5.0 mmol) was dissolved in DCM, and the solution was cooled to 0° C. Ethyl amine (2.0 M in THF, 5.0 mL, 10 mmol) was added dropwise to the acid chloride, and the reaction stirred at 0° C. for 5 min. The ice bath was removed and reaction continued to stir for 3. The solution was washed with brine, dried (Na2SO4), and concentrated in vacuo. The resulting aniline (0.75 g) was used without further purification.

Aufarbeitung

  1. customThe ice bath was removed
  2. customreaction
  3. stirringto stir for 3
  4. washThe solution was washed with brine
  5. dry with materialdried (Na2SO4)
  6. concentrationconcentrated in vacuo
  7. customThe resulting aniline (0.75 g) was used without further purification

Quellen und Nachweise

ORD-Eintrag
ord-2dff38dbaa724d6d8ccc0f12cda4885a
Quelldatensatz
uspto-grants-2005_06
Patentnummer
US06906067B2

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