Diphenyliodonium chloride → Diphenyliodonium tetrakis(pentafluorophenyl)borate

HRID 1079044

Reaktionsgleichung

Reaktionsgleichung von HRID 1079044
[Cl-].[C:2]1([I+:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[F:15][C:16]1[C:21]([B-:22]([C:45]2[C:50]([F:51])=[C:49]([F:52])[C:48]([F:53])=[C:47]([F:54])[C:46]=2[F:55])([C:34]2[C:39]([F:40])=[C:38]([F:41])[C:37]([F:42])=[C:36]([F:43])[C:35]=2[F:44])[C:23]2[C:28]([F:29])=[C:27]([F:30])[C:26]([F:31])=[C:25]([F:32])[C:24]=2[F:33])=[C:20]([F:56])[C:19]([F:57])=[C:18]([F:58])[C:17]=1[F:59].[Li+]>O>[F:51][C:50]1[C:45]([B-:22]([C:23]2[C:28]([F:29])=[C:27]([F:30])[C:26]([F:31])=[C:25]([F:32])[C:24]=2[F:33])([C:21]2[C:20]([F:56])=[C:19]([F:57])[C:18]([F:58])=[C:17]([F:59])[C:16]=2[F:15])[C:34]2[C:35]([F:44])=[C:36]([F:43])[C:37]([F:42])=[C:38]([F:41])[C:39]=2[F:40])=[C:46]([F:55])[C:47]([F:54])=[C:48]([F:53])[C:49]=1[F:52].[C:9]1([I+:8][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1

Komponenten

4

Edukt 2

HCID 73870Diphenyliodonium chlorideHCID 23709652Lithium tetrakis(pentafluorophenyl)borate

Produkt 1

HCID 21918056Diphenyliodonium tetrakis(pentafluorophenyl)borateAusbeute 75 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel2×

Versuchsvorschrift

7.17 g (or 22.6 mmol) of diphenyliodonium chloride were dissolved in 300 ml of water in a 1,000 ml Erlenmeyer flask. 15.52 g (or 22.6 mmol) of lithium tetrakis(pentafluorophenyl)borate in solution in 250 ml of water were added dropwise. The mixture was maintained under stirring for 30 minutes and was then filtered. The filtrate was dried under reduced pressure (133 Pa) overnight with the exclusion of light. 16.33 g (or a yield of 75%) of diphenyliodonium tetrakis(pentafluorophenyl)borate were thus recovered.

Aufarbeitung

  1. temperatureThe mixture was maintained
  2. filtrationwas then filtered
  3. customThe filtrate was dried under reduced pressure (133 Pa) overnight with the exclusion of light
  4. custom16.33 g (or a yield of 75%) of diphenyliodonium tetrakis(pentafluorophenyl)borate were thus recovered

Quellen und Nachweise

ORD-Eintrag
ord-f58cdbe8b04447ef9d9514bdd2bfe940
Quelldatensatz
uspto-grants-1996_08
Patentnummer
US05550265

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