Nitric Acid → 4,4'-Dichlorobenzophenone

HRID 1088002

Reaktionsgleichung

Reaktionsgleichung von HRID 1088002
ClC(Cl)=[C:3]([C:11]1[CH:16]=[CH:15][C:14]([Cl:17])=[CH:13][CH:12]=1)[C:4]1[CH:9]=[CH:8][C:7]([Cl:10])=[CH:6][CH:5]=1.[N+]([O-])(O)=[O:20]>O>[Cl:10][C:7]1[CH:8]=[CH:9][C:4]([C:3]([C:11]2[CH:16]=[CH:15][C:14]([Cl:17])=[CH:13][CH:12]=2)=[O:20])=[CH:5][CH:6]=1

Komponenten

4

Edukt 2

HCID 944Nitric Acid2×HCID 3035P,P'-dde

Produkt 1

HCID 70344,4'-Dichlorobenzophenone

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Reaktionsbedingungen

Temperatur
20 °C

Versuchsvorschrift

A 200 ml flask equipped with a stirrer was charged with 3.3 g of 1,1-dichloro-2,2-bis(4-chlorophenyl)ethylene and then with 50 ml of an aqueous nitric acid solution having a specific gravity of 1.52. The weight ratio of the reaction material to the aqueous solution of nitric acid was 0.043. While vigorously stirring the resulting mixture at room temperature of about 20° C. in a nitrogen atmosphere, they were reacted for 1 hour. The reaction mixture was thereafter added with water, followed by extraction with dichloromethane. After sufficient washing of the dichloromethane layer with water, the extract was analyzed by gas chromatography. As a result, it was found that 1,1-dichloro-2,2-bis(4-chlorophenyl)ethylene was converted in its entirety to 4,4'-dichloro-3,3'-dinitrobenzophenone, but no 4,4'-dichlorobenzophenone was formed at all.

Aufarbeitung

  1. customA 200 ml flask equipped with a stirrer
  2. customwere reacted for 1 hour
  3. extractionfollowed by extraction with dichloromethane
  4. washAfter sufficient washing of the dichloromethane layer with water

Quellen und Nachweise

ORD-Eintrag
ord-8540449c9a62460284eb2c7c138670d1
Quelldatensatz
uspto-grants-1990_10
Patentnummer
US04960945

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