Myristic Acid → Tetradecanoic acid, cadmium salt (2:1)

HRID 1095205

Reaktionsgleichung

Reaktionsgleichung von HRID 1095205
[N+]([O-])([O-])=O.[Cd+2:5].[N+]([O-])([O-])=O.[OH-].[Na+].[C:12]([OH:27])(=[O:26])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25].[C:28]([O-:43])(=[O:42])[CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH3:41].[Na+]>CO>[C:12]([O-:27])(=[O:26])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25].[Cd+2:5].[C:28]([O-:43])(=[O:42])[CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH3:41]

Komponenten

6

Edukt 4

HCID 11005Myristic AcidHCID 14798Sodium HydroxideHCID 25154Cadmium Nitrate2×HCID 23693095Sodium Myristate

Produkt 1

HCID 66290Tetradecanoic acid, cadmium salt (2:1)

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel2×

Versuchsvorschrift

Cadmium nitrate (5 mmol) was dissolved in anhydrous methanol (50 mL). A sodium-myristate solution was prepared by dissolving sodium hydroxide (15 mmol) and myristic acid (15 mmol) in anhydrous methanol (500 mL). Then the cadmium-nitrate solution was added dropwise (one drop per second) into the sodium-myristate solution with vigorous stirring. The resulting white precipitate was washed with methanol three times, and then dried at ˜60° C. under vacuum overnight.

Aufarbeitung

  1. washThe resulting white precipitate was washed with methanol three times
  2. customdried at ˜60° C. under vacuum overnight

Quellen und Nachweise

ORD-Eintrag
ord-f36c17c4339b4b88b5e836b296c9a53d
Quelldatensatz
uspto-grants-2012_03
Patentnummer
US08137457B2

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