HCID 12893740, Verbindung → HCID 12893742, Verbindung

HRID 1106290Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1106290
[O:1]=[C:2]([CH3:13])[CH2:3][CH2:4][CH2:5][C:6]#[C:7][CH2:8][CH2:9][C:10]([OH:12])=[O:11]>C1(C)C=CC=CC=1.[Pd]>[O:1]=[C:2]([CH3:13])[CH2:3][CH2:4][CH2:5]/[CH:6]=[CH:7]\[CH2:8][CH2:9][C:10]([OH:12])=[O:11]

Komponenten

4

Edukt 1

HCID 12893740HCID 12893740, Verbindung

Produkt 1

HCID 12893742HCID 12893742, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23938PalladiumKatalysatorHCID 1140TolueneLösungsmittel

Versuchsvorschrift

10 Grams of the 9-oxodec-4-ynoic acid of Example 18 is hydrogenated at room temperature in toluene containing about 0.5% quinoline with 5% palladium on barium sulfate as catalyst. The toluene solution is washed with 1 N hydrochloric acid, then water. The solution is dried over sodium sulfate and stripped of solvent to give, as a yellow oil, the title product.

Aufarbeitung

  1. washThe toluene solution is washed with 1 N hydrochloric acid
  2. dry with materialThe solution is dried over sodium sulfate
  3. customto give, as a yellow oil

Quellen und Nachweise

ORD-Eintrag
ord-f62e2eadc348493aa266a781a15b4e77
Quelldatensatz
uspto-grants-1982_01
Patentnummer
US04312994

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