Water → 1-Nonyn-4-one

HRID 1106295Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1106295
[CH:1]#[C:2][CH2:3][CH:4]([OH:10])[CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].CC(C)=O.OS(O)(=O)=O.O=[Cr](=O)=O.CCCCCC.O>CC(C)=O>[CH:1]#[C:2][CH2:3][C:4](=[O:10])[CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

Komponenten

6

Edukt 4

HCID 962WaterHCID 8058HexaneHCID 109863221-Nonyn-4-olHCID 131709961Jones' reagent

Produkt 1

HCID 205539671-Nonyn-4-one

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 180AcetoneLösungsmittel

Versuchsvorschrift

A solution of 14 g of 1-nonyn-4-ol in 100 ml of acetone is cooled to 0° and treated dropwise with 70 ml of 2.67 molar Jones reagent with stirring. The reaction mixture is poured into a mixture of hexane and water, the organic layer is separated and washed with water, dried over sodium sulfate, stripped of solvent, and the residue distilled to give the title product.

Aufarbeitung

  1. customthe organic layer is separated
  2. washwashed with water
  3. dry with materialdried over sodium sulfate
  4. distillationthe residue distilled

Quellen und Nachweise

ORD-Eintrag
ord-fdf6124e36594f11b8fdd3d79d68d91a
Quelldatensatz
uspto-grants-1982_01
Patentnummer
US04312994

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