Ethanol → Sodium 8-aminonaphthalene-1,3,5-trisulfonate

HRID 1112193

Reaktionsgleichung

Reaktionsgleichung von HRID 1112193
[NH2:1][C:2]1[C:11]2[C:10]([S:12]([OH:15])(=[O:14])=[O:13])=[CH:9][C:8]([S:16]([OH:19])(=[O:18])=[O:17])=[CH:7][C:6]=2[C:5]([S:20]([OH:23])(=[O:22])=[O:21])=[CH:4][CH:3]=1.C(O)C.[OH-].[Na+:28]>O>[Na+:28].[Na+:28].[Na+:28].[NH2:1][C:2]1[C:11]2[C:10]([S:12]([O-:15])(=[O:14])=[O:13])=[CH:9][C:8]([S:16]([O-:19])(=[O:17])=[O:18])=[CH:7][C:6]=2[C:5]([S:20]([O-:23])(=[O:22])=[O:21])=[CH:4][CH:3]=1

Komponenten

5

Edukt 3

HCID 702EthanolHCID 14798Sodium HydroxideHCID 873558-Aminonaphthalene-1,3,5-trisulfonic acid

Produkt 1

HCID 10343683Sodium 8-aminonaphthalene-1,3,5-trisulfonate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

To a warm solution of 106.4 g of (80.5%) 8-amino-1,3,5-naphthalenetrisulfonic acid in 100 ml of water and 45.0 ml of 5N sodium hydroxide is slowly added 500 ml of absolute ethanol with vigorous stirring for 30 minutes. The mixture iw cooled to room temperature and filtered. The precipitate is washed with 80% aqueous ethanol, ethanol and ether and is dried in vacuo at 110° C. for 16 hours to give 103.7 g of 8-amino-1,3,5-naphthalenetrisulfonic acid trisodium salt.

Aufarbeitung

  1. filtrationfiltered
  2. washThe precipitate is washed with 80% aqueous ethanol, ethanol and ether
  3. customis dried in vacuo at 110° C. for 16 hours

Quellen und Nachweise

ORD-Eintrag
ord-2db68ba84dd24992a29ee26d274a5180
Quelldatensatz
uspto-grants-1978_10
Patentnummer
US04120891

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