Trimethylsilyl iodide → Bistrimethylsilyl-3-cyanopropylphosphonate
Reaktionsgleichung
C([O:3][P:4]([CH2:9][CH2:10][CH2:11][C:12]#[N:13])(=[O:8])[O:5]CC)C.[CH3:14][Si:15](I)([CH3:17])[CH3:16]>C(Cl)(Cl)(Cl)Cl>[CH3:14][Si:15]([O:3][P:4]([CH2:9][CH2:10][CH2:11][C:12]#[N:13])(=[O:8])[O:5][Si:15]([CH3:17])([CH3:16])[CH3:14])([CH3:17])[CH3:16]Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Reaktionsbedingungen
- Temperatur
- 0 °C
Versuchsvorschrift
In an experiment to demonstrate this method, 4.0 g of diethyl-3-cyanopropylphosphonate in 12 ml of carbon tetrachloride, was treated with 5.6 ml of trimethylsilyl iodide. This was cooled to 0° C. and stirred for ten minutes, and allowed to warm to room temperature, forming bis(trimethylsilyl)-3-cyanopropylphosphonate.
Aufarbeitung
- temperatureto warm to room temperature
Quellen und Nachweise
- ORD-Eintrag
- ord-730bd60a21a148278b07a80ebc00947c
- Quelldatensatz
- uspto-grants-1981_11
- Patentnummer
- US04299943
Notizen zur Reaktion
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