Ammonia → 2-(Prop-1-en-2-yl)benzene-1-sulfonamide
Reaktionsgleichung
[NH3:1].[CH3:2][C:3]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[S:11](Cl)(=[O:13])=[O:12])=[CH2:4].[Cl-].[NH4+]>CCOCC>[CH3:2][C:3]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[S:11]([NH2:1])(=[O:13])=[O:12])=[CH2:4]Komponenten
5
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
A solution of anhydrous ammonia (1 ml, 40 mmol) in ether (25 ml) was cooled to 0° and to this was added 2-(1-methylethenyl)benzenesulfonyl chloride of Example 13 (2.9 g, 13 mmol). After stirring for 2 hours at 0° to 5° the ammonium chloride was removed by filtration of the filtrate concentrated to an oil which crystallized on standing to give 2.6 g of the title compound, m.p. 76°-85°.
Aufarbeitung
- customwas removed by filtration of the filtrate
- concentrationconcentrated to an oil which
- customcrystallized
Quellen und Nachweise
- ORD-Eintrag
- ord-79384f60c2d4492c8db5e9ea836732dc
- Quelldatensatz
- uspto-grants-1983_01
- Patentnummer
- US04368069
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