Hydroxyamine hydrochloride → HCID 178487252, Verbindung
Reaktionsgleichung
[CH3:1][O:2][C:3]1[CH:19]=[CH:18][C:17]2[C:8]3[CH:9]=[N:10][C:11]4[C:16]([C:7]=3[C:6](=O)[C:5]=2[CH:4]=1)=[CH:15][CH:14]=[CH:13][CH:12]=4.[NH2:21][OH:22].Cl>C(OC(O)C)C>[CH3:1][O:2][C:3]1[CH:19]=[CH:18][C:17]2[C:8]3[CH:9]=[N:10][C:11]4[C:16]([C:7]=3[C:6](=[N:21][OH:22])[C:5]=2[CH:4]=1)=[CH:15][CH:14]=[CH:13][CH:12]=4Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
To a suspension of compound 5d (0.26 g, 1 mmol) in ethoxyethanol (30 mL) was added NH2OH·HCl (0.20 g, 3 mmol). The reaction mixture was heated with stirring under microwave irradiation (100 W) for 30 min (by TLC monitoring), followed by concentration in vacuo. A solid thus obtained was recrystallized from MeOH to give the title compound 6a (0.20 g, 73% yield).