Potassium Cation → 2-Hydroxymethyl-4-isopropoxy-2,3-dihydro-benzofuran-6-carboxylic acid tert-butyl ester

Reaktionsgleichung

[C:5]([CH3:6])([CH3:7])([CH3:8])[O:9][C:10](=[O:11])[c:12]1[cH:13][c:14]2[c:15]([c:21]([OH:23])[cH:22]1)[CH2:16][CH:17]([CH2:19][OH:20])[O:18]2.[I:1][CH:2]([CH3:3])[CH3:4].[K+:24].[K+:25].[O-:26][C:27]([O-:28])=[O:29].[O:30]=[CH:31][N:32]([CH3:33])[CH3:34]>>[CH:2]([CH3:3])([CH3:4])[O:23][c:21]1[c:15]2[c:14]([cH:13][c:12]([C:10]([O:9][C:5]([CH3:6])([CH3:7])[CH3:8])=[O:11])[cH:22]1)[O:18][CH:17]([CH2:19][OH:20])[CH2:16]2

Komponenten

Edukt 5

HCID 813Potassium Cation2×

HCID 6228Dimethylformamide

HCID 6362Isopropyl iodide

HCID 19660Carbonate Ion

HCID 25067321tert-Butyl 4-hydroxy-2-(hydroxymethyl)-2,3-dihydrobenzofuran-6-carboxylate

Produkt 1

HCID 595601892-Hydroxymethyl-4-isopropoxy-2,3-dihydro-benzofuran-6-carboxylic acid tert-butyl ester

Quellen und Nachweise

ORD-Eintrag: ord-68df786baf52429287532575d8ca61a9
Quelldatensatz: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D

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