Decahydroisoquinoline → 1,2,3,4-Tetrahydroisoquinoline

HRID 1196643

Reaktionsgleichung

Reaktionsgleichung von HRID 1196643
[CH2:1]1[CH:10]2[CH:5]([CH2:6][CH2:7][CH2:8][CH2:9]2)[CH2:4][CH2:3][NH:2]1.N1C2C(CCCC2)CC1.N1CCC2CCCC12.C1C2(CCCCC2)CCN1.C1C2(CCCC2)CCN1.N1CCC2(CC3CC2CC3)C1.N1CCC2(CC3CCC2CC3)C1.C12C3CC1(CC3)CCCN2.N1CCC2CCCCCC12.N1CCC2CC12.C1C2C(CCCC2)CN1.C1C2CCCC2CN1.N1C2C(CCC=C2)CC1.N1CCC2CC=CC12>>[CH2:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH2:4][CH2:3][NH:2]1

Komponenten

15

Edukt 14

HCID 97812DecahydroisoquinolineHCID 107275Octahydro-1H-indoleHCID 110688Octahydrocyclopenta(c)pyrroleHCID 409979OctahydroisoindoleHCID 4188222-Azaspiro(4.5)decaneHCID 4189042-Azaspiro(4.4)nonaneHCID 12400272Octahydrocyclopenta[B]pyrroleHCID 177832232-Azabicyclo[3.1.0]hexaneHCID 184264792,3,3a,4,5,7a-HexahydroindoleHCID 18925328Spiro[bicyclo[2.2.1]heptane-2,3'-pyrrolidine]HCID 18925330Spiro[bicyclo[2.2.2]octane-2,3'-pyrrolidine]HCID 18925332Decahydrocyclohepta[b]pyrroleHCID 196963081,2,3,3a,4,6a-Hexahydrocyclopenta[b]pyrroleHCID 552987402-Azatricyclo[4.3.0.16,9]decane

Produkt 1

HCID 70461,2,3,4-Tetrahydroisoquinoline

Versuchsvorschrift

decahydroisoquinoline (B); octahydroindole (C); octahydrocyclopenta[b]pyrrole (D); 2-azaspiro[4.5]decane (E); 2-azaspiro[4.4]nonane (F); spiro[bicyclo[2.2.1]heptane-2,3'-pyrrolidine] (G); spiro[bicyclo[2.2.2]octane-2,3'-pyrrolidine] (H); 2-azatricyclo[4.3.0.16,9 ]decane (I); decahydrocyclohepta[b]-pyrrole (J); hexahydrocyclopropa[b]pyrrole (K); octahydroisoindole (L); octahydrocyclopenta[c]pyrrole (M); 2,3,3a,4,5,7a-hexahydroindole (N); 1,2,3,3a,4,6a-hexahydrocyclopenta[b]pyrrole (O); all of which can optionally be substituted.

Quellen und Nachweise

ORD-Eintrag
ord-9c987060e0314386a825c8f641bee91c
Quelldatensatz
uspto-grants-1992_05
Patentnummer
US05114962

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