Sodium Sulfite → 1-Naphthalenesulfinic acid

HRID 1197617Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1197617
S([O-])([O-])=O.[Na+].[Na+].[C:7]1([S:17](Cl)(=[O:19])=[O:18])[C:16]2[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=2)[CH:10]=[CH:9][CH:8]=1>O>[C:7]1([S:17]([OH:19])=[O:18])[C:16]2[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=2)[CH:10]=[CH:9][CH:8]=1

Komponenten

4

Edukt 2

HCID 24437Sodium SulfiteHCID 665601-Naphthalenesulfonyl chloride

Produkt 1

HCID 108887691-Naphthalenesulfinic acidAusbeute 95,4 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

189 g of sodium sulfite was dissolved in 600 ml of water, the solution was warmed at a temperature ranging from 60° to 70° C., 68 g of 1-naphthalenesulfonyl chloride was added and then the mixture was reacted at a temperature ranging from 50° to 60° C. for 5 hours. Insolubles were filtered off, the temperature of the reaction solution was brought back to room temperature and the solution was acidified by addition of conc. hydrochloric acid. The resulting precipitates were collected by filtration to give 55 g of 1-naphthalene sulfinic acid.

Aufarbeitung

  1. temperaturethe solution was warmed at a temperature
  2. customranging from 60° to 70° C.
  3. customthe mixture was reacted at a temperature
  4. filtrationInsolubles were filtered off
  5. customwas brought back to room temperature
  6. additionthe solution was acidified by addition of conc. hydrochloric acid
  7. customThe resulting precipitates
  8. filtrationwere collected by filtration

Quellen und Nachweise

ORD-Eintrag
ord-5ea453b8da2c4f9fbe4fa5b4b2d8977a
Quelldatensatz
uspto-grants-1994_01
Patentnummer
US05276124

Notizen zur Reaktion

Wird geladen…