HCID 53672027, Verbindung → 12,12,12-trifluorododecanoic Acid
Reaktionsgleichung
[F:1][C:2]([F:17])([F:16])[CH2:3][CH2:4][CH:5]=[CH:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]([OH:15])=[O:14]>C(O)C.[Pd]>[F:1][C:2]([F:16])([F:17])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]([OH:15])=[O:14]Komponenten
4
Reagenzien, Katalysatoren, Lösungsmittel 2
Versuchsvorschrift
Dissolve 12,12,12-trifluoro-8-dodecenoic acid (1.39g, 5.5 mmol) in ethanol (50 mL) and place in a Paar hydrogenation flask. Add 10% palladium/carbon (500 mg). Charge the vessel to 50 psi and shake for 18 hours. Filter through celite and remove the solvent in vacuo to give 12,12,12-trifluorododecanoic acid.
Aufarbeitung
- additionCharge the vessel to 50 psi
- filtrationFilter through celite
- customremove the solvent in vacuo
Quellen und Nachweise
- ORD-Eintrag
- ord-e9effd9104444fed90e67d06835ccbb4
- Quelldatensatz
- uspto-grants-1994_01
- Patentnummer
- US05278171
Notizen zur Reaktion
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