4,5-Dichlorophthalic acid → 4,5-Dichlorophthalic anhydride

HRID 1199366

Reaktionsgleichung

Reaktionsgleichung von HRID 1199366
[Cl:1][C:2]1[CH:3]=[C:4]([C:12]([OH:14])=[O:13])[C:5](=[CH:9][C:10]=1[Cl:11])[C:6]([OH:8])=O>C(OC(=O)C)(=O)C>[Cl:11][C:10]1[CH:9]=[C:5]2[C:6](=[O:8])[O:14][C:12](=[O:13])[C:4]2=[CH:3][C:2]=1[Cl:1]

Komponenten

3

Edukt 1

HCID 926004,5-Dichlorophthalic acid

Produkt 1

HCID 703344,5-Dichlorophthalic anhydrideAusbeute 87,4 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 7918Acetic AnhydrideLösungsmittel

Versuchsvorschrift

A suspension of 4,5-dichlorophthalic acid [(XVII), X=4-Cl, Y=5-Cl, 50.0 g, 0.213 mol] and acetic anhydride (70 mL) was heated to reflux until dissolution occurred. A distilling head was then attached and 30 mL of distillate was removed. The solution was cooled to room temperature whereupon a precipitate appeared. This solid was filtered, washed with anhydrous ether and dried in vacuo to provide the product (40.4 g, 87%) as a tan solid, m.p. 189°-192° C.

Aufarbeitung

  1. temperaturewas heated
  2. temperatureto reflux until dissolution
  3. custom30 mL of distillate was removed
  4. filtrationThis solid was filtered
  5. washwashed with anhydrous ether
  6. customdried in vacuo

Quellen und Nachweise

ORD-Eintrag
ord-a0baddf346924f6fa2ad3ad86239dc35
Quelldatensatz
uspto-grants-1990_02
Patentnummer
US04900739

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