Potassium thiocyanate → 3-(2-Thiocyanatoethyl)oxetane
Reaktionsgleichung
CC1C=CC(S(O[CH2:12][CH2:13][CH:14]2[CH2:17][O:16][CH2:15]2)(=O)=O)=CC=1.[C:18]([S-:20])#[N:19].[K+]>C(O)C>[S:20]([CH2:12][CH2:13][CH:14]1[CH2:15][O:16][CH2:17]1)[C:18]#[N:19]Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
Using the same reaction conditions, procedure and work up as described for the preparation of Intermediate (I-16b), 2-(oxetan-3-yl)ethyl 4-methyl-benzenesulfonate (1 g, 3.90 mmol) was reacted with KSCN (0.75 g, 7.81 mmol) in ethanol (20 mL) to afford 1.7 g of the crude product which was used for the next step without further purification.
Aufarbeitung
- customthe same reaction conditions, procedure
Quellen und Nachweise
- ORD-Eintrag
- ord-05dde558d8e84b55af7f44b8535c996a
- Quelldatensatz
- uspto-grants-2013_06
- Patentnummer
- US08466289B2
Notizen zur Reaktion
Wird geladen…