HCID 69780004, Verbindung → HCID 69780025, Verbindung
Reaktionsgleichung
[C:1]([O:5][C:6](=[O:28])[NH:7][C:8]1[CH:13]=[C:12]([O:14][CH3:15])[C:11]([N:16]2[CH:20]=[CH:19][CH:18]=[C:17]2[C:21]([CH3:24])([CH3:23])[CH3:22])=[CH:10][C:9]=1[N+:25]([O-])=O)([CH3:4])([CH3:3])[CH3:2]>[Pd]>[C:1]([O:5][C:6](=[O:28])[NH:7][C:8]1[CH:13]=[C:12]([O:14][CH3:15])[C:11]([N:16]2[CH:20]=[CH:19][CH:18]=[C:17]2[C:21]([CH3:24])([CH3:23])[CH3:22])=[CH:10][C:9]=1[NH2:25])([CH3:4])([CH3:2])[CH3:3]Komponenten
3
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
The title compound was prepared from [4-(2-tert.-butyl-pyrrol-1-yl)-5-methoxy-2-nitro-phenyl]-carbamic acid tert.-butyl ester (Example A5) (513 mg, 1.32 mmol) by hydrogenation with 10% Pd/C according to the general procedure J (method a). Obtained as a light brown gum (110 mg).
Quellen und Nachweise
- ORD-Eintrag
- ord-0c41e532f7474444b2686cfcc8d31794
- Quelldatensatz
- uspto-grants-2003_04