HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Ethyl Acrylate → Methyl 4-nitrononanoate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Ethyl Acrylate | HCID 8821 | — |
| Edukt | Potassium Carbonate | HCID 11430 | — |
| Edukt | 1-Nitrohexane | HCID 12589 | — |
| Katalysator | Trioctylmethylammonium chloride | HCID 21218 | — |
| Lösungsmittel | Diethyl Ether | HCID 3283 | — |
| Produkt | Methyl 4-nitrononanoate | HCID 10632556 | — |
Reaktionsschritte
Ex-31a) A suspension of ethyl acrylate, 1-nitrohexane, K2CO3, and Aliquat 336 (6 drops) is sonicated for 5 h. To the reaction is added Et2O . The reaction mixture is filtered, extracted with brine, dried over Na2SO4 (anhydrous), filtered, and concentrated under reduced pressure to give a yellow liquid. The product is purified by column chromatography to give methyl 4-nitrononanoate.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06552052B2 |
| Quelldatensatz | uspto-grants-2003_04 |
| ORD ID | ord-83dc01ddeaa3479db0bbfe65bd494140 |
| Quellennotiz | uspto-grants-2003_04 |