Hydrochloric Acid → HCID 23451800, Verbindung

HRID 1277827Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1277827
[Cl:1][C:2]1[CH:3]=[C:4]([NH:18][C:19](=[O:23])OCC)[CH:5]=[C:6]([Cl:17])[C:7]=1[O:8][C:9]1[CH:14]=[C:13]([Cl:15])[CH:12]=[C:11]([Cl:16])[CH:10]=1.Cl>O>[CH3:19][N:18]1[CH:4]=[CH:3][N:18]([C:4]2[CH:5]=[C:6]([Cl:17])[C:7]([O:8][C:9]3[CH:10]=[C:11]([Cl:16])[CH:12]=[C:13]([Cl:15])[CH:14]=3)=[C:2]([Cl:1])[CH:3]=2)[C:19]1=[O:23]

Komponenten

4

Edukt 2

HCID 313Hydrochloric AcidHCID 54304496Ethyl [3,5-dichloro-4-(3,5-dichlorophenoxy)phenyl]carbamate

Produkt 1

HCID 23451800HCID 23451800, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

Ethyl [3,5-dichloro-4-(3,5-dichlorophenoxy)phenyl]carbamate (0.02 mole), water (30 ml) and concentrated hydrochloric acid (3 ml) are charged into a glass reaction vessel fitted with a mechanical stirrer, thermometer and condenser. The mixture is refluxed for a period of about 30 minutes and then cooled and extracted with ethyl acetate. The extract is washed with dilute aqueous sodium bicarbonate, with two portions of water and is then dried. The ethyl acetate is removed by mild warming under reduced pressure to yield the desired product 1-methyl-3-[3,5-dichloro-4-(3,5-dichlorophenoxy) phenyl]-4-imidazolin-2-one.

Aufarbeitung

  1. customfitted with a mechanical stirrer
  2. temperatureThe mixture is refluxed for a period of about 30 minutes
  3. temperaturecooled
  4. extractionextracted with ethyl acetate
  5. washThe extract is washed with dilute aqueous sodium bicarbonate, with two portions of water
  6. customis then dried
  7. customThe ethyl acetate is removed
  8. temperatureby mild warming under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-28393d8686f44ee0afa8517c0165eadf
Quelldatensatz
uspto-grants-1981_07
Patentnummer
US04279637

Notizen zur Reaktion

Wird geladen…