4-Acetylamino-3,5-bis-trifluoromethylnitrobenzene → HCID 21482728, Verbindung
Reaktionsgleichung
[C:1]([NH:4][C:5]1[C:10]([C:11]([F:14])([F:13])[F:12])=[CH:9][C:8]([N+:15]([O-])=O)=[CH:7][C:6]=1[C:18]([F:21])([F:20])[F:19])(=[O:3])[CH3:2].[H][H]>[Pd].C(O)C>[C:1]([NH:4][C:5]1[C:6]([C:18]([F:20])([F:21])[F:19])=[CH:7][C:8]([NH2:15])=[CH:9][C:10]=1[C:11]([F:12])([F:13])[F:14])(=[O:3])[CH3:2]Komponenten
5
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 2
Versuchsvorschrift
A solution of 7.9 g. of 4-acetylamino-3,5-bis-trifluoromethylnitrobenzene in 200 ml. of ethanol is hydrogenated under 40 lbs. of hydrogen pressure with 1 g. of 5% palladium on charcoal catalyst. When the calculated amount of hydrogen is consumed, the solution is filtered and concentrated in vacuo to give 4-acetylamino-3,5-bis-trifluoromethylaniline.